Crystal structure of bis­(4-meth­oxy­pyridine-κN)(meso-5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)iron(III) perchlorate

In the crystal structure of the title compound, [Fe(C(44)H(28)N(4))(C(6)H(7)NO)(2)]ClO(4), the Fe(III) ions are coordinated in an octa­hedral fashion by four N atoms of the porphyrin moiety and two N atoms of two 4-meth­oxy­pyridine ligands into discrete complexes that are located on inversion cente...

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Detalles Bibliográficos
Autores principales: Peters, Morten K., Näther, Christian, Herges, Rainer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658977/
https://www.ncbi.nlm.nih.gov/pubmed/31391961
http://dx.doi.org/10.1107/S2056989019006194
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author Peters, Morten K.
Näther, Christian
Herges, Rainer
author_facet Peters, Morten K.
Näther, Christian
Herges, Rainer
author_sort Peters, Morten K.
collection PubMed
description In the crystal structure of the title compound, [Fe(C(44)H(28)N(4))(C(6)H(7)NO)(2)]ClO(4), the Fe(III) ions are coordinated in an octa­hedral fashion by four N atoms of the porphyrin moiety and two N atoms of two 4-meth­oxy­pyridine ligands into discrete complexes that are located on inversion centers. Charge-balance is achieved by perchlorate anions that are disordered around twofold rotation axes. In the crystal structure, the discrete cationic complexes and the perchlorate anions are arranged into layers with weak C—H⋯O inter­actions between the cations and the anions. The porphyrin moieties of neighboring layers show a herringbone-like arrangement.
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spelling pubmed-66589772019-08-07 Crystal structure of bis­(4-meth­oxy­pyridine-κN)(meso-5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)iron(III) perchlorate Peters, Morten K. Näther, Christian Herges, Rainer Acta Crystallogr E Crystallogr Commun Research Communications In the crystal structure of the title compound, [Fe(C(44)H(28)N(4))(C(6)H(7)NO)(2)]ClO(4), the Fe(III) ions are coordinated in an octa­hedral fashion by four N atoms of the porphyrin moiety and two N atoms of two 4-meth­oxy­pyridine ligands into discrete complexes that are located on inversion centers. Charge-balance is achieved by perchlorate anions that are disordered around twofold rotation axes. In the crystal structure, the discrete cationic complexes and the perchlorate anions are arranged into layers with weak C—H⋯O inter­actions between the cations and the anions. The porphyrin moieties of neighboring layers show a herringbone-like arrangement. International Union of Crystallography 2019-05-10 /pmc/articles/PMC6658977/ /pubmed/31391961 http://dx.doi.org/10.1107/S2056989019006194 Text en © Peters et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Peters, Morten K.
Näther, Christian
Herges, Rainer
Crystal structure of bis­(4-meth­oxy­pyridine-κN)(meso-5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)iron(III) perchlorate
title Crystal structure of bis­(4-meth­oxy­pyridine-κN)(meso-5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)iron(III) perchlorate
title_full Crystal structure of bis­(4-meth­oxy­pyridine-κN)(meso-5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)iron(III) perchlorate
title_fullStr Crystal structure of bis­(4-meth­oxy­pyridine-κN)(meso-5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)iron(III) perchlorate
title_full_unstemmed Crystal structure of bis­(4-meth­oxy­pyridine-κN)(meso-5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)iron(III) perchlorate
title_short Crystal structure of bis­(4-meth­oxy­pyridine-κN)(meso-5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N,N′,N′′,N′′′)iron(III) perchlorate
title_sort crystal structure of bis­(4-meth­oxy­pyridine-κn)(meso-5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n,n′,n′′,n′′′)iron(iii) perchlorate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658977/
https://www.ncbi.nlm.nih.gov/pubmed/31391961
http://dx.doi.org/10.1107/S2056989019006194
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