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Crystal structures of a series of 6-aryl-1,3-diphenyl­fulvenes

The synthesis and crystal structures of a series of 6-aryl­fuvlenes (fulvene is 5-methyl­idene­cyclo­penta-1,3-diene) with varying methyl­ation patterns on the 6-phenyl substituent are reported, namely 6-(3-methyl­phen­yl)-1,3-di­phenyl­fulvene (C(25)H(20)), 6-(4-methyl­phen­yl)-1,3-di­phenyl­fulven...

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Detalles Bibliográficos
Autores principales: Peloquin, Andrew J., Adas, Sonya K., Iacono, Scott T., Balaich, Gary J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658983/
https://www.ncbi.nlm.nih.gov/pubmed/31391978
http://dx.doi.org/10.1107/S205698901900700X
Descripción
Sumario:The synthesis and crystal structures of a series of 6-aryl­fuvlenes (fulvene is 5-methyl­idene­cyclo­penta-1,3-diene) with varying methyl­ation patterns on the 6-phenyl substituent are reported, namely 6-(3-methyl­phen­yl)-1,3-di­phenyl­fulvene (C(25)H(20)), 6-(4-methyl­phen­yl)-1,3-di­phenyl­fulvene (C(25)H(20)), 6-mesityl-3-di­phenyl­fulvene (C(27)H(24)) and 6-(2,3,4,5,6-penta­methyl­phen­yl)-1,3-di­phenyl­fulvene (C(29)H(28)). The bond lengths are typical of those observed in related fulvenes. A network of C—H⋯π ring inter­actions consolidates the packing in each structure.