Crystal structures of a series of 6-aryl-1,3-diphenyl­fulvenes

The synthesis and crystal structures of a series of 6-aryl­fuvlenes (fulvene is 5-methyl­idene­cyclo­penta-1,3-diene) with varying methyl­ation patterns on the 6-phenyl substituent are reported, namely 6-(3-methyl­phen­yl)-1,3-di­phenyl­fulvene (C(25)H(20)), 6-(4-methyl­phen­yl)-1,3-di­phenyl­fulven...

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Autores principales: Peloquin, Andrew J., Adas, Sonya K., Iacono, Scott T., Balaich, Gary J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658983/
https://www.ncbi.nlm.nih.gov/pubmed/31391978
http://dx.doi.org/10.1107/S205698901900700X
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author Peloquin, Andrew J.
Adas, Sonya K.
Iacono, Scott T.
Balaich, Gary J.
author_facet Peloquin, Andrew J.
Adas, Sonya K.
Iacono, Scott T.
Balaich, Gary J.
author_sort Peloquin, Andrew J.
collection PubMed
description The synthesis and crystal structures of a series of 6-aryl­fuvlenes (fulvene is 5-methyl­idene­cyclo­penta-1,3-diene) with varying methyl­ation patterns on the 6-phenyl substituent are reported, namely 6-(3-methyl­phen­yl)-1,3-di­phenyl­fulvene (C(25)H(20)), 6-(4-methyl­phen­yl)-1,3-di­phenyl­fulvene (C(25)H(20)), 6-mesityl-3-di­phenyl­fulvene (C(27)H(24)) and 6-(2,3,4,5,6-penta­methyl­phen­yl)-1,3-di­phenyl­fulvene (C(29)H(28)). The bond lengths are typical of those observed in related fulvenes. A network of C—H⋯π ring inter­actions consolidates the packing in each structure.
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spelling pubmed-66589832019-08-07 Crystal structures of a series of 6-aryl-1,3-diphenyl­fulvenes Peloquin, Andrew J. Adas, Sonya K. Iacono, Scott T. Balaich, Gary J. Acta Crystallogr E Crystallogr Commun Research Communications The synthesis and crystal structures of a series of 6-aryl­fuvlenes (fulvene is 5-methyl­idene­cyclo­penta-1,3-diene) with varying methyl­ation patterns on the 6-phenyl substituent are reported, namely 6-(3-methyl­phen­yl)-1,3-di­phenyl­fulvene (C(25)H(20)), 6-(4-methyl­phen­yl)-1,3-di­phenyl­fulvene (C(25)H(20)), 6-mesityl-3-di­phenyl­fulvene (C(27)H(24)) and 6-(2,3,4,5,6-penta­methyl­phen­yl)-1,3-di­phenyl­fulvene (C(29)H(28)). The bond lengths are typical of those observed in related fulvenes. A network of C—H⋯π ring inter­actions consolidates the packing in each structure. International Union of Crystallography 2019-05-21 /pmc/articles/PMC6658983/ /pubmed/31391978 http://dx.doi.org/10.1107/S205698901900700X Text en © Peloquin et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Peloquin, Andrew J.
Adas, Sonya K.
Iacono, Scott T.
Balaich, Gary J.
Crystal structures of a series of 6-aryl-1,3-diphenyl­fulvenes
title Crystal structures of a series of 6-aryl-1,3-diphenyl­fulvenes
title_full Crystal structures of a series of 6-aryl-1,3-diphenyl­fulvenes
title_fullStr Crystal structures of a series of 6-aryl-1,3-diphenyl­fulvenes
title_full_unstemmed Crystal structures of a series of 6-aryl-1,3-diphenyl­fulvenes
title_short Crystal structures of a series of 6-aryl-1,3-diphenyl­fulvenes
title_sort crystal structures of a series of 6-aryl-1,3-diphenyl­fulvenes
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658983/
https://www.ncbi.nlm.nih.gov/pubmed/31391978
http://dx.doi.org/10.1107/S205698901900700X
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