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Crystal structure and Hirshfeld surface analysis of diiodido{N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium(II)
In each of the two independent molecules in the asymmetric unit of the title compound, [CdI(2)(C(18)H(14)N(4)O)], the N,O,N′-tridentate N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide ligand and two iodide anions form an I(2)N(2)O pentacoordination sphere, with a distorted...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659320/ https://www.ncbi.nlm.nih.gov/pubmed/31392025 http://dx.doi.org/10.1107/S2056989019008831 |
Sumario: | In each of the two independent molecules in the asymmetric unit of the title compound, [CdI(2)(C(18)H(14)N(4)O)], the N,O,N′-tridentate N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide ligand and two iodide anions form an I(2)N(2)O pentacoordination sphere, with a distorted square-pyramidal geometry, with an I atom in the apical position. Both molecules feature an intramolecular N—H⋯N hydrogen bond. In the crystal, weak aromatic π–π stacking interactions [centroid–centroid separation = 3.830 (2) Å] link the molecules into dimers. |
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