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Crystal structure and Hirshfeld surface analysis of diiodido{N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium(II)
In each of the two independent molecules in the asymmetric unit of the title compound, [CdI(2)(C(18)H(14)N(4)O)], the N,O,N′-tridentate N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide ligand and two iodide anions form an I(2)N(2)O pentacoordination sphere, with a distorted...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659320/ https://www.ncbi.nlm.nih.gov/pubmed/31392025 http://dx.doi.org/10.1107/S2056989019008831 |
| _version_ | 1783439113848881152 |
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| author | Atioğlu, Zeliha Afkhami, Farhad Akbari Akkurt, Mehmet Khandar, Ali Akbar Choquesillo-Lazarte, Duane |
| author_facet | Atioğlu, Zeliha Afkhami, Farhad Akbari Akkurt, Mehmet Khandar, Ali Akbar Choquesillo-Lazarte, Duane |
| author_sort | Atioğlu, Zeliha |
| collection | PubMed |
| description | In each of the two independent molecules in the asymmetric unit of the title compound, [CdI(2)(C(18)H(14)N(4)O)], the N,O,N′-tridentate N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide ligand and two iodide anions form an I(2)N(2)O pentacoordination sphere, with a distorted square-pyramidal geometry, with an I atom in the apical position. Both molecules feature an intramolecular N—H⋯N hydrogen bond. In the crystal, weak aromatic π–π stacking interactions [centroid–centroid separation = 3.830 (2) Å] link the molecules into dimers. |
| format | Online Article Text |
| id | pubmed-6659320 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2019 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-66593202019-08-07 Crystal structure and Hirshfeld surface analysis of diiodido{N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium(II) Atioğlu, Zeliha Afkhami, Farhad Akbari Akkurt, Mehmet Khandar, Ali Akbar Choquesillo-Lazarte, Duane Acta Crystallogr E Crystallogr Commun Research Communications In each of the two independent molecules in the asymmetric unit of the title compound, [CdI(2)(C(18)H(14)N(4)O)], the N,O,N′-tridentate N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide ligand and two iodide anions form an I(2)N(2)O pentacoordination sphere, with a distorted square-pyramidal geometry, with an I atom in the apical position. Both molecules feature an intramolecular N—H⋯N hydrogen bond. In the crystal, weak aromatic π–π stacking interactions [centroid–centroid separation = 3.830 (2) Å] link the molecules into dimers. International Union of Crystallography 2019-06-25 /pmc/articles/PMC6659320/ /pubmed/31392025 http://dx.doi.org/10.1107/S2056989019008831 Text en © Atioğlu et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
| spellingShingle | Research Communications Atioğlu, Zeliha Afkhami, Farhad Akbari Akkurt, Mehmet Khandar, Ali Akbar Choquesillo-Lazarte, Duane Crystal structure and Hirshfeld surface analysis of diiodido{N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium(II) |
| title | Crystal structure and Hirshfeld surface analysis of diiodido{N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2)
N′,O}cadmium(II) |
| title_full | Crystal structure and Hirshfeld surface analysis of diiodido{N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2)
N′,O}cadmium(II) |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of diiodido{N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2)
N′,O}cadmium(II) |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of diiodido{N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2)
N′,O}cadmium(II) |
| title_short | Crystal structure and Hirshfeld surface analysis of diiodido{N′-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2)
N′,O}cadmium(II) |
| title_sort | crystal structure and hirshfeld surface analysis of diiodido{n′-[(e)-(phenyl)(pyridin-2-yl-κn)methylidene]pyridine-2-carbohydrazide-κ(2)
n′,o}cadmium(ii) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659320/ https://www.ncbi.nlm.nih.gov/pubmed/31392025 http://dx.doi.org/10.1107/S2056989019008831 |
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