Inter­molecular hydrogen bonding in isostructural pincer complexes [OH-((t-Bu)POCOP(t-Bu))MCl] (M = Pd and Pt)

In the crystal structure of the isostructural title compounds, namely {2,6-bis­[(di-tert-butyl­phosphan­yl)­oxy]-4-hy­droxy­phen­yl}chlorido­palladium(II), [Pd(C(22)H(39)O(3)P(2))Cl], 1, and {2,6-bis­[(di-tert-butyl­phosphan­yl)­oxy]-4-hy­droxy­phen­yl}chlorido­platinum(II), [Pt(C(22)H(39)O(3)P(2))C...

Descripción completa

Detalles Bibliográficos
Autores principales: Joksch, Markus, Spannenberg, Anke, Beweries, Torsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659334/
https://www.ncbi.nlm.nih.gov/pubmed/31392015
http://dx.doi.org/10.1107/S2056989019008491
Descripción
Sumario:In the crystal structure of the isostructural title compounds, namely {2,6-bis­[(di-tert-butyl­phosphan­yl)­oxy]-4-hy­droxy­phen­yl}chlorido­palladium(II), [Pd(C(22)H(39)O(3)P(2))Cl], 1, and {2,6-bis­[(di-tert-butyl­phosphan­yl)­oxy]-4-hy­droxy­phen­yl}chlorido­platinum(II), [Pt(C(22)H(39)O(3)P(2))Cl], 2, the metal centres are coordinated in a distorted square-planar fashion by the POCOP pincer fragment and the chloride ligand. Both complexes form strong hydrogen-bonded chain structures through an inter­action of the OH group in the 4-position of the aromatic POCOP backbone with the halide ligand.

Ejemplares similares