Inter­molecular hydrogen bonding in isostructural pincer complexes [OH-((t-Bu)POCOP(t-Bu))MCl] (M = Pd and Pt)

In the crystal structure of the isostructural title compounds, namely {2,6-bis­[(di-tert-butyl­phosphan­yl)­oxy]-4-hy­droxy­phen­yl}chlorido­palladium(II), [Pd(C(22)H(39)O(3)P(2))Cl], 1, and {2,6-bis­[(di-tert-butyl­phosphan­yl)­oxy]-4-hy­droxy­phen­yl}chlorido­platinum(II), [Pt(C(22)H(39)O(3)P(2))C...

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Detalles Bibliográficos
Autores principales: Joksch, Markus, Spannenberg, Anke, Beweries, Torsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659334/
https://www.ncbi.nlm.nih.gov/pubmed/31392015
http://dx.doi.org/10.1107/S2056989019008491
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author Joksch, Markus
Spannenberg, Anke
Beweries, Torsten
author_facet Joksch, Markus
Spannenberg, Anke
Beweries, Torsten
author_sort Joksch, Markus
collection PubMed
description In the crystal structure of the isostructural title compounds, namely {2,6-bis­[(di-tert-butyl­phosphan­yl)­oxy]-4-hy­droxy­phen­yl}chlorido­palladium(II), [Pd(C(22)H(39)O(3)P(2))Cl], 1, and {2,6-bis­[(di-tert-butyl­phosphan­yl)­oxy]-4-hy­droxy­phen­yl}chlorido­platinum(II), [Pt(C(22)H(39)O(3)P(2))Cl], 2, the metal centres are coordinated in a distorted square-planar fashion by the POCOP pincer fragment and the chloride ligand. Both complexes form strong hydrogen-bonded chain structures through an inter­action of the OH group in the 4-position of the aromatic POCOP backbone with the halide ligand.
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spelling pubmed-66593342019-08-07 Inter­molecular hydrogen bonding in isostructural pincer complexes [OH-((t-Bu)POCOP(t-Bu))MCl] (M = Pd and Pt) Joksch, Markus Spannenberg, Anke Beweries, Torsten Acta Crystallogr E Crystallogr Commun Research Communications In the crystal structure of the isostructural title compounds, namely {2,6-bis­[(di-tert-butyl­phosphan­yl)­oxy]-4-hy­droxy­phen­yl}chlorido­palladium(II), [Pd(C(22)H(39)O(3)P(2))Cl], 1, and {2,6-bis­[(di-tert-butyl­phosphan­yl)­oxy]-4-hy­droxy­phen­yl}chlorido­platinum(II), [Pt(C(22)H(39)O(3)P(2))Cl], 2, the metal centres are coordinated in a distorted square-planar fashion by the POCOP pincer fragment and the chloride ligand. Both complexes form strong hydrogen-bonded chain structures through an inter­action of the OH group in the 4-position of the aromatic POCOP backbone with the halide ligand. International Union of Crystallography 2019-06-21 /pmc/articles/PMC6659334/ /pubmed/31392015 http://dx.doi.org/10.1107/S2056989019008491 Text en © Joksch et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Joksch, Markus
Spannenberg, Anke
Beweries, Torsten
Inter­molecular hydrogen bonding in isostructural pincer complexes [OH-((t-Bu)POCOP(t-Bu))MCl] (M = Pd and Pt)
title Inter­molecular hydrogen bonding in isostructural pincer complexes [OH-((t-Bu)POCOP(t-Bu))MCl] (M = Pd and Pt)
title_full Inter­molecular hydrogen bonding in isostructural pincer complexes [OH-((t-Bu)POCOP(t-Bu))MCl] (M = Pd and Pt)
title_fullStr Inter­molecular hydrogen bonding in isostructural pincer complexes [OH-((t-Bu)POCOP(t-Bu))MCl] (M = Pd and Pt)
title_full_unstemmed Inter­molecular hydrogen bonding in isostructural pincer complexes [OH-((t-Bu)POCOP(t-Bu))MCl] (M = Pd and Pt)
title_short Inter­molecular hydrogen bonding in isostructural pincer complexes [OH-((t-Bu)POCOP(t-Bu))MCl] (M = Pd and Pt)
title_sort inter­molecular hydrogen bonding in isostructural pincer complexes [oh-((t-bu)pocop(t-bu))mcl] (m = pd and pt)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659334/
https://www.ncbi.nlm.nih.gov/pubmed/31392015
http://dx.doi.org/10.1107/S2056989019008491
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