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Crystal structure of N-(diphenylphosphoryl)-2-methoxybenzamide
In the title compound, C(20)H(18)NO(3)P, the C=O and P=O groups of the carbacylamidophosphate (CAPh) fragments are located in a synclinal position relative to each other and are pre-organized for bidentate chelate coordination of metal ions. The N—H group is involved in the formation of an intram...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659338/ https://www.ncbi.nlm.nih.gov/pubmed/31391999 http://dx.doi.org/10.1107/S205698901900762X |
Sumario: | In the title compound, C(20)H(18)NO(3)P, the C=O and P=O groups of the carbacylamidophosphate (CAPh) fragments are located in a synclinal position relative to each other and are pre-organized for bidentate chelate coordination of metal ions. The N—H group is involved in the formation of an intramolecular hydrogen bond. In the crystal, molecules do not form strong intermolecular interactions but the molecules are linked via weak C—H⋯π interactions, forming chains along [001]. |
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