Crystal structure of N-(di­phenyl­phosphor­yl)-2-meth­oxy­benzamide

In the title compound, C(20)H(18)NO(3)P, the C=O and P=O groups of the carbacyl­amido­phosphate (CAPh) fragments are located in a synclinal position relative to each other and are pre-organized for bidentate chelate coordination of metal ions. The N—H group is involved in the formation of an intra­m...

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Autores principales: Trush, Victor A., Kariaka, Nataliia S., Dyakonenko, Viktoriya V., Shishkina, Svitlana V., Amirkhanov, Vladimir M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659338/
https://www.ncbi.nlm.nih.gov/pubmed/31391999
http://dx.doi.org/10.1107/S205698901900762X
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author Trush, Victor A.
Kariaka, Nataliia S.
Dyakonenko, Viktoriya V.
Shishkina, Svitlana V.
Amirkhanov, Vladimir M.
author_facet Trush, Victor A.
Kariaka, Nataliia S.
Dyakonenko, Viktoriya V.
Shishkina, Svitlana V.
Amirkhanov, Vladimir M.
author_sort Trush, Victor A.
collection PubMed
description In the title compound, C(20)H(18)NO(3)P, the C=O and P=O groups of the carbacyl­amido­phosphate (CAPh) fragments are located in a synclinal position relative to each other and are pre-organized for bidentate chelate coordination of metal ions. The N—H group is involved in the formation of an intra­molecular hydrogen bond. In the crystal, mol­ecules do not form strong inter­molecular inter­actions but the mol­ecules are linked via weak C—H⋯π inter­actions, forming chains along [001].
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spelling pubmed-66593382019-08-07 Crystal structure of N-(di­phenyl­phosphor­yl)-2-meth­oxy­benzamide Trush, Victor A. Kariaka, Nataliia S. Dyakonenko, Viktoriya V. Shishkina, Svitlana V. Amirkhanov, Vladimir M. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(20)H(18)NO(3)P, the C=O and P=O groups of the carbacyl­amido­phosphate (CAPh) fragments are located in a synclinal position relative to each other and are pre-organized for bidentate chelate coordination of metal ions. The N—H group is involved in the formation of an intra­molecular hydrogen bond. In the crystal, mol­ecules do not form strong inter­molecular inter­actions but the mol­ecules are linked via weak C—H⋯π inter­actions, forming chains along [001]. International Union of Crystallography 2019-06-04 /pmc/articles/PMC6659338/ /pubmed/31391999 http://dx.doi.org/10.1107/S205698901900762X Text en © Trush et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Trush, Victor A.
Kariaka, Nataliia S.
Dyakonenko, Viktoriya V.
Shishkina, Svitlana V.
Amirkhanov, Vladimir M.
Crystal structure of N-(di­phenyl­phosphor­yl)-2-meth­oxy­benzamide
title Crystal structure of N-(di­phenyl­phosphor­yl)-2-meth­oxy­benzamide
title_full Crystal structure of N-(di­phenyl­phosphor­yl)-2-meth­oxy­benzamide
title_fullStr Crystal structure of N-(di­phenyl­phosphor­yl)-2-meth­oxy­benzamide
title_full_unstemmed Crystal structure of N-(di­phenyl­phosphor­yl)-2-meth­oxy­benzamide
title_short Crystal structure of N-(di­phenyl­phosphor­yl)-2-meth­oxy­benzamide
title_sort crystal structure of n-(di­phenyl­phosphor­yl)-2-meth­oxy­benzamide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6659338/
https://www.ncbi.nlm.nih.gov/pubmed/31391999
http://dx.doi.org/10.1107/S205698901900762X
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