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Phase Engineering for Highly Efficient Quasi-Two-Dimensional All-Inorganic Perovskite Light-Emitting Diodes via Adjusting the Ratio of Cs Cation
Quasi-two-dimensional (2D) perovskites have received intensive attention as a new class of luminescent materials owing to large exciton binding energy and high photoluminescence efficiency. However, there usually contains a mixture of phases in these materials, and excessive low-dimensional phase pe...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer US
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6661056/ https://www.ncbi.nlm.nih.gov/pubmed/31352526 http://dx.doi.org/10.1186/s11671-019-3076-x |
Sumario: | Quasi-two-dimensional (2D) perovskites have received intensive attention as a new class of luminescent materials owing to large exciton binding energy and high photoluminescence efficiency. However, there usually contains a mixture of phases in these materials, and excessive low-dimensional phase perovskite is harmful for luminescence efficiency owing to the strong exciton-phonon quenching at the room temperature. Herein, a simple and effective method is proposed to suppress the growth of low-dimensional phase components in quasi-2D perovskite film via carefully adjusting the molar ratio of cesium bromide (CsBr) and phenylpropylammonium bromide (PPABr). The device based on this optimized film has achieved a peak brightness of 2921 cd m(−2) and peak current efficiency of 1.38 cd A(−1), far away higher than that of the pristine CsPbBr(3) device. This research proves a new way for modulating the phase composition in quasi-2D perovskites to fabricate highly efficient perovskite light-emitting diodes (PeLEDs). |
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