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Phase Engineering for Highly Efficient Quasi-Two-Dimensional All-Inorganic Perovskite Light-Emitting Diodes via Adjusting the Ratio of Cs Cation

Quasi-two-dimensional (2D) perovskites have received intensive attention as a new class of luminescent materials owing to large exciton binding energy and high photoluminescence efficiency. However, there usually contains a mixture of phases in these materials, and excessive low-dimensional phase pe...

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Autores principales: Xu, Xiaoqiang, Wang, Zijun, Yu, Junsheng, Li, Lu, Yan, Xingwu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6661056/
https://www.ncbi.nlm.nih.gov/pubmed/31352526
http://dx.doi.org/10.1186/s11671-019-3076-x
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author Xu, Xiaoqiang
Wang, Zijun
Yu, Junsheng
Li, Lu
Yan, Xingwu
author_facet Xu, Xiaoqiang
Wang, Zijun
Yu, Junsheng
Li, Lu
Yan, Xingwu
author_sort Xu, Xiaoqiang
collection PubMed
description Quasi-two-dimensional (2D) perovskites have received intensive attention as a new class of luminescent materials owing to large exciton binding energy and high photoluminescence efficiency. However, there usually contains a mixture of phases in these materials, and excessive low-dimensional phase perovskite is harmful for luminescence efficiency owing to the strong exciton-phonon quenching at the room temperature. Herein, a simple and effective method is proposed to suppress the growth of low-dimensional phase components in quasi-2D perovskite film via carefully adjusting the molar ratio of cesium bromide (CsBr) and phenylpropylammonium bromide (PPABr). The device based on this optimized film has achieved a peak brightness of 2921 cd m(−2) and peak current efficiency of 1.38 cd A(−1), far away higher than that of the pristine CsPbBr(3) device. This research proves a new way for modulating the phase composition in quasi-2D perovskites to fabricate highly efficient perovskite light-emitting diodes (PeLEDs).
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spelling pubmed-66610562019-08-07 Phase Engineering for Highly Efficient Quasi-Two-Dimensional All-Inorganic Perovskite Light-Emitting Diodes via Adjusting the Ratio of Cs Cation Xu, Xiaoqiang Wang, Zijun Yu, Junsheng Li, Lu Yan, Xingwu Nanoscale Res Lett Nano Express Quasi-two-dimensional (2D) perovskites have received intensive attention as a new class of luminescent materials owing to large exciton binding energy and high photoluminescence efficiency. However, there usually contains a mixture of phases in these materials, and excessive low-dimensional phase perovskite is harmful for luminescence efficiency owing to the strong exciton-phonon quenching at the room temperature. Herein, a simple and effective method is proposed to suppress the growth of low-dimensional phase components in quasi-2D perovskite film via carefully adjusting the molar ratio of cesium bromide (CsBr) and phenylpropylammonium bromide (PPABr). The device based on this optimized film has achieved a peak brightness of 2921 cd m(−2) and peak current efficiency of 1.38 cd A(−1), far away higher than that of the pristine CsPbBr(3) device. This research proves a new way for modulating the phase composition in quasi-2D perovskites to fabricate highly efficient perovskite light-emitting diodes (PeLEDs). Springer US 2019-07-27 /pmc/articles/PMC6661056/ /pubmed/31352526 http://dx.doi.org/10.1186/s11671-019-3076-x Text en © The Author(s). 2019 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Nano Express
Xu, Xiaoqiang
Wang, Zijun
Yu, Junsheng
Li, Lu
Yan, Xingwu
Phase Engineering for Highly Efficient Quasi-Two-Dimensional All-Inorganic Perovskite Light-Emitting Diodes via Adjusting the Ratio of Cs Cation
title Phase Engineering for Highly Efficient Quasi-Two-Dimensional All-Inorganic Perovskite Light-Emitting Diodes via Adjusting the Ratio of Cs Cation
title_full Phase Engineering for Highly Efficient Quasi-Two-Dimensional All-Inorganic Perovskite Light-Emitting Diodes via Adjusting the Ratio of Cs Cation
title_fullStr Phase Engineering for Highly Efficient Quasi-Two-Dimensional All-Inorganic Perovskite Light-Emitting Diodes via Adjusting the Ratio of Cs Cation
title_full_unstemmed Phase Engineering for Highly Efficient Quasi-Two-Dimensional All-Inorganic Perovskite Light-Emitting Diodes via Adjusting the Ratio of Cs Cation
title_short Phase Engineering for Highly Efficient Quasi-Two-Dimensional All-Inorganic Perovskite Light-Emitting Diodes via Adjusting the Ratio of Cs Cation
title_sort phase engineering for highly efficient quasi-two-dimensional all-inorganic perovskite light-emitting diodes via adjusting the ratio of cs cation
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6661056/
https://www.ncbi.nlm.nih.gov/pubmed/31352526
http://dx.doi.org/10.1186/s11671-019-3076-x
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