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In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks
We report a series of Pd K-edge and Pt L(3)-edge X-ray absorption spectra (XAS) collected in situ during thermal treatment of functionalized UiO-67-Pd and UiO-67-Pt metal-organic frameworks in inert and reducing atmospheres. We present raw synchrotron data from three subsequent experiments at differ...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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Elsevier
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6661504/ https://www.ncbi.nlm.nih.gov/pubmed/31384654 http://dx.doi.org/10.1016/j.dib.2019.104280 |
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author | Bugaev, Aram L. Skorynina, Alina A. Kamyshova, Elizaveta G. Lomachenko, Kirill A. Guda, Alexander A. Soldatov, Alexander V. Lamberti, Carlo |
author_facet | Bugaev, Aram L. Skorynina, Alina A. Kamyshova, Elizaveta G. Lomachenko, Kirill A. Guda, Alexander A. Soldatov, Alexander V. Lamberti, Carlo |
author_sort | Bugaev, Aram L. |
collection | PubMed |
description | We report a series of Pd K-edge and Pt L(3)-edge X-ray absorption spectra (XAS) collected in situ during thermal treatment of functionalized UiO-67-Pd and UiO-67-Pt metal-organic frameworks in inert and reducing atmospheres. We present raw synchrotron data from three subsequent experiments at different beamlines, normalized XAS spectra and k(2)-weighted oscillatory χ(k) functions extracted from one of the datasets. Pd K-edge spectra were collected for the samples in 5% H(2)/He, 3% H(2)/He and pure He in the temperature range from room temperature (RT) to 450 °C. Pt L(3)-edge were collected for the samples in 3% H(2)/He, 10% H(2)/He and pure He in the temperature range from RT to 300 °C. All spectra are reported together with the used atmosphere and temperature. For the analysis of all reported datasets, please see “Evolution of Pt and Pd species in functionalized UiO-67 metal-organic frameworks”. Fourier-analysis of Pd K-edge is reported in “Formation and growth of Pd nanoparticles in UiO-67 MOF by in situ EXAFS”. |
format | Online Article Text |
id | pubmed-6661504 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-66615042019-08-05 In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks Bugaev, Aram L. Skorynina, Alina A. Kamyshova, Elizaveta G. Lomachenko, Kirill A. Guda, Alexander A. Soldatov, Alexander V. Lamberti, Carlo Data Brief Chemistry We report a series of Pd K-edge and Pt L(3)-edge X-ray absorption spectra (XAS) collected in situ during thermal treatment of functionalized UiO-67-Pd and UiO-67-Pt metal-organic frameworks in inert and reducing atmospheres. We present raw synchrotron data from three subsequent experiments at different beamlines, normalized XAS spectra and k(2)-weighted oscillatory χ(k) functions extracted from one of the datasets. Pd K-edge spectra were collected for the samples in 5% H(2)/He, 3% H(2)/He and pure He in the temperature range from room temperature (RT) to 450 °C. Pt L(3)-edge were collected for the samples in 3% H(2)/He, 10% H(2)/He and pure He in the temperature range from RT to 300 °C. All spectra are reported together with the used atmosphere and temperature. For the analysis of all reported datasets, please see “Evolution of Pt and Pd species in functionalized UiO-67 metal-organic frameworks”. Fourier-analysis of Pd K-edge is reported in “Formation and growth of Pd nanoparticles in UiO-67 MOF by in situ EXAFS”. Elsevier 2019-07-17 /pmc/articles/PMC6661504/ /pubmed/31384654 http://dx.doi.org/10.1016/j.dib.2019.104280 Text en © 2019 The Authors http://creativecommons.org/licenses/by/4.0/ This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Chemistry Bugaev, Aram L. Skorynina, Alina A. Kamyshova, Elizaveta G. Lomachenko, Kirill A. Guda, Alexander A. Soldatov, Alexander V. Lamberti, Carlo In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks |
title | In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks |
title_full | In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks |
title_fullStr | In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks |
title_full_unstemmed | In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks |
title_short | In situ X-ray absorption spectroscopy data during formation of active Pt- and Pd-sites in functionalized UiO-67 metal-organic frameworks |
title_sort | in situ x-ray absorption spectroscopy data during formation of active pt- and pd-sites in functionalized uio-67 metal-organic frameworks |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6661504/ https://www.ncbi.nlm.nih.gov/pubmed/31384654 http://dx.doi.org/10.1016/j.dib.2019.104280 |
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