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Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold

[Image: see text] Use of chiral solvents in asymmetric synthesis as a sole source of enantioselection remains largely unexplored in organic synthesis. We found that the use of a helical macromolecular catalyst of which helical chirality is dynamically formed in chiral solvents allowed several mechan...

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Detalles Bibliográficos
Autores principales: Nagata, Yuuya, Takeda, Ryohei, Suginome, Michinori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6661863/
https://www.ncbi.nlm.nih.gov/pubmed/31404214
http://dx.doi.org/10.1021/acscentsci.9b00330