Cargando…

Mesoporous graphene adsorbents for the removal of toluene and xylene at various concentrations and its reusability

As novel technologies have been developed, emissions of gases of volatile organic compounds (VOCs) have increased. These affect human health and are destructive to the environment, contributing to global warming. Hence, regulations on the use of volatile organic compounds have been strengthened. The...

Descripción completa

Detalles Bibliográficos
Autores principales: Lim, Sun Taek, Kim, Ji Hoon, Lee, Chang Yeon, Koo, Sangmo, Jerng, Dong-Wook, Wongwises, Somchai, Ahn, Ho Seon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6662692/
https://www.ncbi.nlm.nih.gov/pubmed/31358796
http://dx.doi.org/10.1038/s41598-019-47100-z
_version_ 1783439691643617280
author Lim, Sun Taek
Kim, Ji Hoon
Lee, Chang Yeon
Koo, Sangmo
Jerng, Dong-Wook
Wongwises, Somchai
Ahn, Ho Seon
author_facet Lim, Sun Taek
Kim, Ji Hoon
Lee, Chang Yeon
Koo, Sangmo
Jerng, Dong-Wook
Wongwises, Somchai
Ahn, Ho Seon
author_sort Lim, Sun Taek
collection PubMed
description As novel technologies have been developed, emissions of gases of volatile organic compounds (VOCs) have increased. These affect human health and are destructive to the environment, contributing to global warming. Hence, regulations on the use of volatile organic compounds have been strengthened. Therefore, powerful adsorbents are required for volatile organic compounds gases. In this study, we used graphene powder with a mesoporous structure to adsorb aromatic compounds such as toluene and xylene at various concentrations (30, 50, 100 ppm). The configuration and chemical composition of the adsorbents were characterized using scanning electron microscopy (SEM), N(2) adsorption-desorption isotherm measurements, and X-ray photoelectron spectroscopy (XPS). The adsorption test was carried out using a polypropylene filter, which contained the adsorbents (0.25 g), with analysis performed using a gas detector. Compared to graphite oxide (GO) powder, the specific surface area of thermally expanded graphene powder (TEGP800) increased significantly, to 542 m(2) g(−1), and its chemical properties transformed from polar to non-polar. Thermally expanded graphene powder exhibits high adsorption efficiency for toluene (92.7–98.3%) and xylene (96.7–98%) and its reusability is remarkable, being at least 91%.
format Online
Article
Text
id pubmed-6662692
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher Nature Publishing Group UK
record_format MEDLINE/PubMed
spelling pubmed-66626922019-08-02 Mesoporous graphene adsorbents for the removal of toluene and xylene at various concentrations and its reusability Lim, Sun Taek Kim, Ji Hoon Lee, Chang Yeon Koo, Sangmo Jerng, Dong-Wook Wongwises, Somchai Ahn, Ho Seon Sci Rep Article As novel technologies have been developed, emissions of gases of volatile organic compounds (VOCs) have increased. These affect human health and are destructive to the environment, contributing to global warming. Hence, regulations on the use of volatile organic compounds have been strengthened. Therefore, powerful adsorbents are required for volatile organic compounds gases. In this study, we used graphene powder with a mesoporous structure to adsorb aromatic compounds such as toluene and xylene at various concentrations (30, 50, 100 ppm). The configuration and chemical composition of the adsorbents were characterized using scanning electron microscopy (SEM), N(2) adsorption-desorption isotherm measurements, and X-ray photoelectron spectroscopy (XPS). The adsorption test was carried out using a polypropylene filter, which contained the adsorbents (0.25 g), with analysis performed using a gas detector. Compared to graphite oxide (GO) powder, the specific surface area of thermally expanded graphene powder (TEGP800) increased significantly, to 542 m(2) g(−1), and its chemical properties transformed from polar to non-polar. Thermally expanded graphene powder exhibits high adsorption efficiency for toluene (92.7–98.3%) and xylene (96.7–98%) and its reusability is remarkable, being at least 91%. Nature Publishing Group UK 2019-07-29 /pmc/articles/PMC6662692/ /pubmed/31358796 http://dx.doi.org/10.1038/s41598-019-47100-z Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Lim, Sun Taek
Kim, Ji Hoon
Lee, Chang Yeon
Koo, Sangmo
Jerng, Dong-Wook
Wongwises, Somchai
Ahn, Ho Seon
Mesoporous graphene adsorbents for the removal of toluene and xylene at various concentrations and its reusability
title Mesoporous graphene adsorbents for the removal of toluene and xylene at various concentrations and its reusability
title_full Mesoporous graphene adsorbents for the removal of toluene and xylene at various concentrations and its reusability
title_fullStr Mesoporous graphene adsorbents for the removal of toluene and xylene at various concentrations and its reusability
title_full_unstemmed Mesoporous graphene adsorbents for the removal of toluene and xylene at various concentrations and its reusability
title_short Mesoporous graphene adsorbents for the removal of toluene and xylene at various concentrations and its reusability
title_sort mesoporous graphene adsorbents for the removal of toluene and xylene at various concentrations and its reusability
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6662692/
https://www.ncbi.nlm.nih.gov/pubmed/31358796
http://dx.doi.org/10.1038/s41598-019-47100-z
work_keys_str_mv AT limsuntaek mesoporousgrapheneadsorbentsfortheremovaloftolueneandxyleneatvariousconcentrationsanditsreusability
AT kimjihoon mesoporousgrapheneadsorbentsfortheremovaloftolueneandxyleneatvariousconcentrationsanditsreusability
AT leechangyeon mesoporousgrapheneadsorbentsfortheremovaloftolueneandxyleneatvariousconcentrationsanditsreusability
AT koosangmo mesoporousgrapheneadsorbentsfortheremovaloftolueneandxyleneatvariousconcentrationsanditsreusability
AT jerngdongwook mesoporousgrapheneadsorbentsfortheremovaloftolueneandxyleneatvariousconcentrationsanditsreusability
AT wongwisessomchai mesoporousgrapheneadsorbentsfortheremovaloftolueneandxyleneatvariousconcentrationsanditsreusability
AT ahnhoseon mesoporousgrapheneadsorbentsfortheremovaloftolueneandxyleneatvariousconcentrationsanditsreusability