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The cyclopropylcarbinyl route to γ-silyl carbocations
The mesylate derivative of cis-1-hydroxymethyl-2-trimethylsilylcyclopropane has been prepared, along with a number of related mesylates and triflates with substituents on the 1-position. These substrates all solvolyze in CD(3)CO(2)D to give products derived from cyclopropylcarbinyl cations that unde...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6664402/ https://www.ncbi.nlm.nih.gov/pubmed/31435448 http://dx.doi.org/10.3762/bjoc.15.170 |