Host–guest interactions in nor-seco-cucurbit[10]uril: novel guest-dependent molecular recognition and stereoisomerism

The unique monomer and excimer fluorescence emissions of pyrene were first exploited as distinctly photophysical signals to identify the possible diastereomers of guests within nor-seco-cucurbit[10]uril (NS-CB[10]) cavities. Further experiments revealed that balancing the hydrophilic and hydrophobic...

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Detalles Bibliográficos
Autores principales: Zhang, Xiaodong, Wu, Wei, Tao, Zhu, Ni, Xin-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6664405/
https://www.ncbi.nlm.nih.gov/pubmed/31435444
http://dx.doi.org/10.3762/bjoc.15.166
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author Zhang, Xiaodong
Wu, Wei
Tao, Zhu
Ni, Xin-Long
author_facet Zhang, Xiaodong
Wu, Wei
Tao, Zhu
Ni, Xin-Long
author_sort Zhang, Xiaodong
collection PubMed
description The unique monomer and excimer fluorescence emissions of pyrene were first exploited as distinctly photophysical signals to identify the possible diastereomers of guests within nor-seco-cucurbit[10]uril (NS-CB[10]) cavities. Further experiments revealed that balancing the hydrophilic and hydrophobic effects of the guest in aqueous solution can improve the molecular recognition and binding ability of NS-CB[10].
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spelling pubmed-66644052019-08-21 Host–guest interactions in nor-seco-cucurbit[10]uril: novel guest-dependent molecular recognition and stereoisomerism Zhang, Xiaodong Wu, Wei Tao, Zhu Ni, Xin-Long Beilstein J Org Chem Full Research Paper The unique monomer and excimer fluorescence emissions of pyrene were first exploited as distinctly photophysical signals to identify the possible diastereomers of guests within nor-seco-cucurbit[10]uril (NS-CB[10]) cavities. Further experiments revealed that balancing the hydrophilic and hydrophobic effects of the guest in aqueous solution can improve the molecular recognition and binding ability of NS-CB[10]. Beilstein-Institut 2019-07-19 /pmc/articles/PMC6664405/ /pubmed/31435444 http://dx.doi.org/10.3762/bjoc.15.166 Text en Copyright © 2019, Zhang et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Zhang, Xiaodong
Wu, Wei
Tao, Zhu
Ni, Xin-Long
Host–guest interactions in nor-seco-cucurbit[10]uril: novel guest-dependent molecular recognition and stereoisomerism
title Host–guest interactions in nor-seco-cucurbit[10]uril: novel guest-dependent molecular recognition and stereoisomerism
title_full Host–guest interactions in nor-seco-cucurbit[10]uril: novel guest-dependent molecular recognition and stereoisomerism
title_fullStr Host–guest interactions in nor-seco-cucurbit[10]uril: novel guest-dependent molecular recognition and stereoisomerism
title_full_unstemmed Host–guest interactions in nor-seco-cucurbit[10]uril: novel guest-dependent molecular recognition and stereoisomerism
title_short Host–guest interactions in nor-seco-cucurbit[10]uril: novel guest-dependent molecular recognition and stereoisomerism
title_sort host–guest interactions in nor-seco-cucurbit[10]uril: novel guest-dependent molecular recognition and stereoisomerism
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6664405/
https://www.ncbi.nlm.nih.gov/pubmed/31435444
http://dx.doi.org/10.3762/bjoc.15.166
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