Metal-free mechanochemical oxidations in Ertalyte(®) jars

Aimed at eliminating or at least significantly reducing the use of solvents, sodium hypochlorite pentahydrate crystals (NaOCl·5H(2)O) in the presence of a catalytic amount of a nitrosyl radical (TEMPO or AZADO) have been successfully used to induce mechanochemical oxidative processes on several stru...

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Autores principales: Porcheddu, Andrea, Delogu, Francesco, De Luca, Lidia, Fattuoni, Claudia, Colacino, Evelina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6664414/
https://www.ncbi.nlm.nih.gov/pubmed/31435450
http://dx.doi.org/10.3762/bjoc.15.172
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author Porcheddu, Andrea
Delogu, Francesco
De Luca, Lidia
Fattuoni, Claudia
Colacino, Evelina
author_facet Porcheddu, Andrea
Delogu, Francesco
De Luca, Lidia
Fattuoni, Claudia
Colacino, Evelina
author_sort Porcheddu, Andrea
collection PubMed
description Aimed at eliminating or at least significantly reducing the use of solvents, sodium hypochlorite pentahydrate crystals (NaOCl·5H(2)O) in the presence of a catalytic amount of a nitrosyl radical (TEMPO or AZADO) have been successfully used to induce mechanochemical oxidative processes on several structurally different primary and secondary alcohols. The proposed redox process is safe, inexpensive and performing effectively, especially on the macroscale. Herein, an Ertalyte(®) jar has been successfully used, for the first time, in a mechanochemical process.
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spelling pubmed-66644142019-08-21 Metal-free mechanochemical oxidations in Ertalyte(®) jars Porcheddu, Andrea Delogu, Francesco De Luca, Lidia Fattuoni, Claudia Colacino, Evelina Beilstein J Org Chem Full Research Paper Aimed at eliminating or at least significantly reducing the use of solvents, sodium hypochlorite pentahydrate crystals (NaOCl·5H(2)O) in the presence of a catalytic amount of a nitrosyl radical (TEMPO or AZADO) have been successfully used to induce mechanochemical oxidative processes on several structurally different primary and secondary alcohols. The proposed redox process is safe, inexpensive and performing effectively, especially on the macroscale. Herein, an Ertalyte(®) jar has been successfully used, for the first time, in a mechanochemical process. Beilstein-Institut 2019-07-25 /pmc/articles/PMC6664414/ /pubmed/31435450 http://dx.doi.org/10.3762/bjoc.15.172 Text en Copyright © 2019, Porcheddu et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Porcheddu, Andrea
Delogu, Francesco
De Luca, Lidia
Fattuoni, Claudia
Colacino, Evelina
Metal-free mechanochemical oxidations in Ertalyte(®) jars
title Metal-free mechanochemical oxidations in Ertalyte(®) jars
title_full Metal-free mechanochemical oxidations in Ertalyte(®) jars
title_fullStr Metal-free mechanochemical oxidations in Ertalyte(®) jars
title_full_unstemmed Metal-free mechanochemical oxidations in Ertalyte(®) jars
title_short Metal-free mechanochemical oxidations in Ertalyte(®) jars
title_sort metal-free mechanochemical oxidations in ertalyte(®) jars
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6664414/
https://www.ncbi.nlm.nih.gov/pubmed/31435450
http://dx.doi.org/10.3762/bjoc.15.172
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