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Recent Progress in Metal–Organic Framework (MOF) Based Luminescent Chemodosimeters

Metal–organic frameworks (MOFs), as a class of crystalline hybrid architectures, consist of metal ions and organic ligands and have displayed great potential in luminescent sensing applications due to their tunable structures and unique photophysical properties. Until now, many studies have been rep...

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Detalles Bibliográficos
Autores principales: Hao, Yuanqiang, Chen, Shu, Zhou, Yanli, Zhang, Yintang, Xu, Maotian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6669767/
https://www.ncbi.nlm.nih.gov/pubmed/31277318
http://dx.doi.org/10.3390/nano9070974
Descripción
Sumario:Metal–organic frameworks (MOFs), as a class of crystalline hybrid architectures, consist of metal ions and organic ligands and have displayed great potential in luminescent sensing applications due to their tunable structures and unique photophysical properties. Until now, many studies have been reported on the development of MOF-based luminescent sensors, which can be classified into two major categories: MOF chemosensors based on reversible host–guest interactions and MOF chemodosimeters based on the irreversible reactions between targets with a probe. In this review, we summarize the recently developed luminescent MOF-based chemodosimeters for various analytes, including H(2)S, HClO, biothiols, fluoride ions, redox-active biomolecules, Hg(2+), and CN(−). In addition, some remaining challenges and future perspectives in this area are also discussed.