Weathering in a world without terrestrial life recorded in the Mesoproterozoic Velkerri Formation

Today the terrestrial surface drives biogeochemical cycles on Earth through chemical weathering reactions mediated by the biological influence of soils. Prior to the expansion of life on to land, abiotic weathering may have resulted in different boundary conditions affecting the composition of the biosphere. Here we show a striking difference in weathering produced minerals preserved in the Mesoproterozoic Velkerri Formation. While the bulk chemistry and mineralogy is dominated by illite similar to many modern mudstones, application of a novel microbeam technology reveals that the initial detrital minerals were composed of mica (28%) and feldspar (45%) with only a trace amount (<2%) of typical soil formed clay minerals. The majority of illite and the high Al(2)O(3) fraction previously interpreted as a weathering signal, is present as a replacement of feldspar and mica. These sediments record physical erosion with limited pedogenic clay mineral formation implying fundamentally different weathering pathways.