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Ring‐Opening Regio‐, Diastereo‐, and Enantioselective 1,3‐Chlorochalcogenation of Cyclopropyl Carbaldehydes

meso‐Cyclopropyl carbaldehydes are treated in the presence of an organocatalyst with sulfenyl and selenyl chlorides to afford 1,3‐chlorochalcogenated products. The transformation is achieved by a merged iminium–enamine activation. The enantioselective desymmetrization reaction, leading to three adja...

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Detalles Bibliográficos
Autores principales:	Wallbaum, Jan, Garve, Lennart K. B., Jones, Peter G., Werz, Daniel B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2016
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6680189/ https://www.ncbi.nlm.nih.gov/pubmed/27868248 http://dx.doi.org/10.1002/chem.201605265

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