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Preparation of Biowax Esters in Continuous Flow Conditions

[Image: see text] Biowaxes synthesized from vegetable fatty acids are an alternative to petrochemical paraffins. A simple way of access to these compounds involves Fisher-type esterification of long-chain acids and alcohols under acidic conditions, but long reaction times and harsh conditions are co...

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Autores principales: Caputo, Daniela, Casiello, Michele, Laurenza, Amelita Grazia, Fracassi, Francesco, Fusco, Caterina, Nacci, Angelo, D’Accolti, Lucia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6681984/
https://www.ncbi.nlm.nih.gov/pubmed/31460345
http://dx.doi.org/10.1021/acsomega.9b00861
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author Caputo, Daniela
Casiello, Michele
Laurenza, Amelita Grazia
Fracassi, Francesco
Fusco, Caterina
Nacci, Angelo
D’Accolti, Lucia
author_facet Caputo, Daniela
Casiello, Michele
Laurenza, Amelita Grazia
Fracassi, Francesco
Fusco, Caterina
Nacci, Angelo
D’Accolti, Lucia
author_sort Caputo, Daniela
collection PubMed
description [Image: see text] Biowaxes synthesized from vegetable fatty acids are an alternative to petrochemical paraffins. A simple way of access to these compounds involves Fisher-type esterification of long-chain acids and alcohols under acidic conditions, but long reaction times and harsh conditions are commonly required. In this study, for the first time in the literature, biowax esters are prepared under flow conditions cutting dramatically both reaction times (from 12 h to 30 min) and temperature conditions, with respect to batch procedures (from 90–120 °C to 55 °C). This approach brings substantial improvements to the biowax synthesis process from an economic and environmental point of view, thus making the method up-scalable to the industrial level.
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spelling pubmed-66819842019-08-27 Preparation of Biowax Esters in Continuous Flow Conditions Caputo, Daniela Casiello, Michele Laurenza, Amelita Grazia Fracassi, Francesco Fusco, Caterina Nacci, Angelo D’Accolti, Lucia ACS Omega [Image: see text] Biowaxes synthesized from vegetable fatty acids are an alternative to petrochemical paraffins. A simple way of access to these compounds involves Fisher-type esterification of long-chain acids and alcohols under acidic conditions, but long reaction times and harsh conditions are commonly required. In this study, for the first time in the literature, biowax esters are prepared under flow conditions cutting dramatically both reaction times (from 12 h to 30 min) and temperature conditions, with respect to batch procedures (from 90–120 °C to 55 °C). This approach brings substantial improvements to the biowax synthesis process from an economic and environmental point of view, thus making the method up-scalable to the industrial level. American Chemical Society 2019-07-17 /pmc/articles/PMC6681984/ /pubmed/31460345 http://dx.doi.org/10.1021/acsomega.9b00861 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Caputo, Daniela
Casiello, Michele
Laurenza, Amelita Grazia
Fracassi, Francesco
Fusco, Caterina
Nacci, Angelo
D’Accolti, Lucia
Preparation of Biowax Esters in Continuous Flow Conditions
title Preparation of Biowax Esters in Continuous Flow Conditions
title_full Preparation of Biowax Esters in Continuous Flow Conditions
title_fullStr Preparation of Biowax Esters in Continuous Flow Conditions
title_full_unstemmed Preparation of Biowax Esters in Continuous Flow Conditions
title_short Preparation of Biowax Esters in Continuous Flow Conditions
title_sort preparation of biowax esters in continuous flow conditions
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6681984/
https://www.ncbi.nlm.nih.gov/pubmed/31460345
http://dx.doi.org/10.1021/acsomega.9b00861
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