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Preparation of Biowax Esters in Continuous Flow Conditions
[Image: see text] Biowaxes synthesized from vegetable fatty acids are an alternative to petrochemical paraffins. A simple way of access to these compounds involves Fisher-type esterification of long-chain acids and alcohols under acidic conditions, but long reaction times and harsh conditions are co...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6681984/ https://www.ncbi.nlm.nih.gov/pubmed/31460345 http://dx.doi.org/10.1021/acsomega.9b00861 |
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author | Caputo, Daniela Casiello, Michele Laurenza, Amelita Grazia Fracassi, Francesco Fusco, Caterina Nacci, Angelo D’Accolti, Lucia |
author_facet | Caputo, Daniela Casiello, Michele Laurenza, Amelita Grazia Fracassi, Francesco Fusco, Caterina Nacci, Angelo D’Accolti, Lucia |
author_sort | Caputo, Daniela |
collection | PubMed |
description | [Image: see text] Biowaxes synthesized from vegetable fatty acids are an alternative to petrochemical paraffins. A simple way of access to these compounds involves Fisher-type esterification of long-chain acids and alcohols under acidic conditions, but long reaction times and harsh conditions are commonly required. In this study, for the first time in the literature, biowax esters are prepared under flow conditions cutting dramatically both reaction times (from 12 h to 30 min) and temperature conditions, with respect to batch procedures (from 90–120 °C to 55 °C). This approach brings substantial improvements to the biowax synthesis process from an economic and environmental point of view, thus making the method up-scalable to the industrial level. |
format | Online Article Text |
id | pubmed-6681984 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-66819842019-08-27 Preparation of Biowax Esters in Continuous Flow Conditions Caputo, Daniela Casiello, Michele Laurenza, Amelita Grazia Fracassi, Francesco Fusco, Caterina Nacci, Angelo D’Accolti, Lucia ACS Omega [Image: see text] Biowaxes synthesized from vegetable fatty acids are an alternative to petrochemical paraffins. A simple way of access to these compounds involves Fisher-type esterification of long-chain acids and alcohols under acidic conditions, but long reaction times and harsh conditions are commonly required. In this study, for the first time in the literature, biowax esters are prepared under flow conditions cutting dramatically both reaction times (from 12 h to 30 min) and temperature conditions, with respect to batch procedures (from 90–120 °C to 55 °C). This approach brings substantial improvements to the biowax synthesis process from an economic and environmental point of view, thus making the method up-scalable to the industrial level. American Chemical Society 2019-07-17 /pmc/articles/PMC6681984/ /pubmed/31460345 http://dx.doi.org/10.1021/acsomega.9b00861 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Caputo, Daniela Casiello, Michele Laurenza, Amelita Grazia Fracassi, Francesco Fusco, Caterina Nacci, Angelo D’Accolti, Lucia Preparation of Biowax Esters in Continuous Flow Conditions |
title | Preparation of Biowax Esters in Continuous Flow Conditions |
title_full | Preparation of Biowax Esters in Continuous Flow Conditions |
title_fullStr | Preparation of Biowax Esters in Continuous Flow Conditions |
title_full_unstemmed | Preparation of Biowax Esters in Continuous Flow Conditions |
title_short | Preparation of Biowax Esters in Continuous Flow Conditions |
title_sort | preparation of biowax esters in continuous flow conditions |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6681984/ https://www.ncbi.nlm.nih.gov/pubmed/31460345 http://dx.doi.org/10.1021/acsomega.9b00861 |
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