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Role of Ruthenium in the Dielectric, Magnetic Properties of Nickel Ferrite (Ru–NiFe(2)O(4)) Nanoparticles and Their Application in Hydrogen Sensors

[Image: see text] In this work, Ru-doped nickel ferrites (NiFe(2)O(4)) were synthesized by a chemical co-precipitation method. Subsequently, they were annealed at different temperatures. The crystallinity of the samples was evaluated using X-ray diffraction and the morphology of the samples was inve...

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Autores principales: Manikandan, Venkatraman, Mirzaei, Ali, Vigneselvan, Sivasubramaniam, Kavita, Srikanti, Mane, Rajaram Sakharam, Kim, Sang Sub, Chandrasekaran, Joseph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6681989/
https://www.ncbi.nlm.nih.gov/pubmed/31460418
http://dx.doi.org/10.1021/acsomega.9b01562
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author Manikandan, Venkatraman
Mirzaei, Ali
Vigneselvan, Sivasubramaniam
Kavita, Srikanti
Mane, Rajaram Sakharam
Kim, Sang Sub
Chandrasekaran, Joseph
author_facet Manikandan, Venkatraman
Mirzaei, Ali
Vigneselvan, Sivasubramaniam
Kavita, Srikanti
Mane, Rajaram Sakharam
Kim, Sang Sub
Chandrasekaran, Joseph
author_sort Manikandan, Venkatraman
collection PubMed
description [Image: see text] In this work, Ru-doped nickel ferrites (NiFe(2)O(4)) were synthesized by a chemical co-precipitation method. Subsequently, they were annealed at different temperatures. The crystallinity of the samples was evaluated using X-ray diffraction and the morphology of the samples was investigated by scanning electron microscopy and transmission electron microscopy. Dielectric constants and dielectric loss were studied. Ru-doped nickel ferrite samples showed relatively low dielectric constant and loss. Also, the dielectric constant and loss decreased with increasing annealing temperature. Vibrational sample magnetometer analysis shows the hysteresis loop of a soft magnetic nature and the relevant parameters (M(r,)M(s) and H(c)) have low values that confirmed the nature of the material. Subsequently, gas sensors were fabricated to study hydrogen-sensing properties. The gas sensors showed a response to hydrogen gas at a low temperature (100 °C) with selective response in the presence of NH(3) and C(2)H(5)OH gases. The reasons for electrical, magnetic, and sensing behavior of the samples were discussed in detail.
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spelling pubmed-66819892019-08-27 Role of Ruthenium in the Dielectric, Magnetic Properties of Nickel Ferrite (Ru–NiFe(2)O(4)) Nanoparticles and Their Application in Hydrogen Sensors Manikandan, Venkatraman Mirzaei, Ali Vigneselvan, Sivasubramaniam Kavita, Srikanti Mane, Rajaram Sakharam Kim, Sang Sub Chandrasekaran, Joseph ACS Omega [Image: see text] In this work, Ru-doped nickel ferrites (NiFe(2)O(4)) were synthesized by a chemical co-precipitation method. Subsequently, they were annealed at different temperatures. The crystallinity of the samples was evaluated using X-ray diffraction and the morphology of the samples was investigated by scanning electron microscopy and transmission electron microscopy. Dielectric constants and dielectric loss were studied. Ru-doped nickel ferrite samples showed relatively low dielectric constant and loss. Also, the dielectric constant and loss decreased with increasing annealing temperature. Vibrational sample magnetometer analysis shows the hysteresis loop of a soft magnetic nature and the relevant parameters (M(r,)M(s) and H(c)) have low values that confirmed the nature of the material. Subsequently, gas sensors were fabricated to study hydrogen-sensing properties. The gas sensors showed a response to hydrogen gas at a low temperature (100 °C) with selective response in the presence of NH(3) and C(2)H(5)OH gases. The reasons for electrical, magnetic, and sensing behavior of the samples were discussed in detail. American Chemical Society 2019-07-31 /pmc/articles/PMC6681989/ /pubmed/31460418 http://dx.doi.org/10.1021/acsomega.9b01562 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Manikandan, Venkatraman
Mirzaei, Ali
Vigneselvan, Sivasubramaniam
Kavita, Srikanti
Mane, Rajaram Sakharam
Kim, Sang Sub
Chandrasekaran, Joseph
Role of Ruthenium in the Dielectric, Magnetic Properties of Nickel Ferrite (Ru–NiFe(2)O(4)) Nanoparticles and Their Application in Hydrogen Sensors
title Role of Ruthenium in the Dielectric, Magnetic Properties of Nickel Ferrite (Ru–NiFe(2)O(4)) Nanoparticles and Their Application in Hydrogen Sensors
title_full Role of Ruthenium in the Dielectric, Magnetic Properties of Nickel Ferrite (Ru–NiFe(2)O(4)) Nanoparticles and Their Application in Hydrogen Sensors
title_fullStr Role of Ruthenium in the Dielectric, Magnetic Properties of Nickel Ferrite (Ru–NiFe(2)O(4)) Nanoparticles and Their Application in Hydrogen Sensors
title_full_unstemmed Role of Ruthenium in the Dielectric, Magnetic Properties of Nickel Ferrite (Ru–NiFe(2)O(4)) Nanoparticles and Their Application in Hydrogen Sensors
title_short Role of Ruthenium in the Dielectric, Magnetic Properties of Nickel Ferrite (Ru–NiFe(2)O(4)) Nanoparticles and Their Application in Hydrogen Sensors
title_sort role of ruthenium in the dielectric, magnetic properties of nickel ferrite (ru–nife(2)o(4)) nanoparticles and their application in hydrogen sensors
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6681989/
https://www.ncbi.nlm.nih.gov/pubmed/31460418
http://dx.doi.org/10.1021/acsomega.9b01562
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