Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb(2+) and Cr(2)O(7)(2–)

[Image: see text] A three-dimensional supramolecular framework containing both left- and right-handed helixes, {[Zn(TTPA)Cl(2)]·1.63H(2)O}(n) (1), has been converted to a novel octanuclear cluster containing a metal–organic framework, [Zn(8)(ptptp)(6)Cl(2)](ClO(4))(2)·4CH(3)OH·2H(2)O (1b), induced b...

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Autores principales: Yang, Dan-Dan, Liu, Yue, Li, ShuangShuang, Cheng, Lin, Wang, Ying, Zhang, Ying-Xin, Chen, Kai, Gao, Yi-Xuan, Ren, Peng, Day, Gregory S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6682107/
https://www.ncbi.nlm.nih.gov/pubmed/31460254
http://dx.doi.org/10.1021/acsomega.9b00680
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author Yang, Dan-Dan
Liu, Yue
Li, ShuangShuang
Cheng, Lin
Wang, Ying
Zhang, Ying-Xin
Chen, Kai
Gao, Yi-Xuan
Ren, Peng
Day, Gregory S.
Wang, Ying
author_facet Yang, Dan-Dan
Liu, Yue
Li, ShuangShuang
Cheng, Lin
Wang, Ying
Zhang, Ying-Xin
Chen, Kai
Gao, Yi-Xuan
Ren, Peng
Day, Gregory S.
Wang, Ying
author_sort Yang, Dan-Dan
collection PubMed
description [Image: see text] A three-dimensional supramolecular framework containing both left- and right-handed helixes, {[Zn(TTPA)Cl(2)]·1.63H(2)O}(n) (1), has been converted to a novel octanuclear cluster containing a metal–organic framework, [Zn(8)(ptptp)(6)Cl(2)](ClO(4))(2)·4CH(3)OH·2H(2)O (1b), induced by ligand rearrangement during a solvothermal process. The luminescent properties of 1b indicate that the material can act as a selective probe toward Pb(2+) and Cr(2)O(7)(2–).
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spelling pubmed-66821072019-08-27 Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb(2+) and Cr(2)O(7)(2–) Yang, Dan-Dan Liu, Yue Li, ShuangShuang Cheng, Lin Wang, Ying Zhang, Ying-Xin Chen, Kai Gao, Yi-Xuan Ren, Peng Day, Gregory S. Wang, Ying ACS Omega [Image: see text] A three-dimensional supramolecular framework containing both left- and right-handed helixes, {[Zn(TTPA)Cl(2)]·1.63H(2)O}(n) (1), has been converted to a novel octanuclear cluster containing a metal–organic framework, [Zn(8)(ptptp)(6)Cl(2)](ClO(4))(2)·4CH(3)OH·2H(2)O (1b), induced by ligand rearrangement during a solvothermal process. The luminescent properties of 1b indicate that the material can act as a selective probe toward Pb(2+) and Cr(2)O(7)(2–). American Chemical Society 2019-07-01 /pmc/articles/PMC6682107/ /pubmed/31460254 http://dx.doi.org/10.1021/acsomega.9b00680 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Yang, Dan-Dan
Liu, Yue
Li, ShuangShuang
Cheng, Lin
Wang, Ying
Zhang, Ying-Xin
Chen, Kai
Gao, Yi-Xuan
Ren, Peng
Day, Gregory S.
Wang, Ying
Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb(2+) and Cr(2)O(7)(2–)
title Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb(2+) and Cr(2)O(7)(2–)
title_full Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb(2+) and Cr(2)O(7)(2–)
title_fullStr Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb(2+) and Cr(2)O(7)(2–)
title_full_unstemmed Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb(2+) and Cr(2)O(7)(2–)
title_short Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb(2+) and Cr(2)O(7)(2–)
title_sort ligand-rearrangement-induced transformation from a 3d supramolecular network to a discrete octanuclear cluster: a good detector for pb(2+) and cr(2)o(7)(2–)
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6682107/
https://www.ncbi.nlm.nih.gov/pubmed/31460254
http://dx.doi.org/10.1021/acsomega.9b00680
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