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H(2)O(2) photoproduction inside H(2)O and H(2)O:O(2) ices at 20–140 K

We report the results of laboratory measurements of H(2)O(2) production inside thin (50 nm thickness) H(2)O and H(2)O:O(2) ice samples irradiated by 121.6 nm photons at different temperatures. In the case of H(2)O ice, H(2)O(2) is formed at the temperatures below 60 К. In the case of H(2)O:O(2) ice,...

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Detalles Bibliográficos
Autores principales: Kulikov, Mikhail Yu., Feigin, Alexander M., Schrems, Otto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6684810/
https://www.ncbi.nlm.nih.gov/pubmed/31388066
http://dx.doi.org/10.1038/s41598-019-47915-w
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author Kulikov, Mikhail Yu.
Feigin, Alexander M.
Schrems, Otto
author_facet Kulikov, Mikhail Yu.
Feigin, Alexander M.
Schrems, Otto
author_sort Kulikov, Mikhail Yu.
collection PubMed
description We report the results of laboratory measurements of H(2)O(2) production inside thin (50 nm thickness) H(2)O and H(2)O:O(2) ice samples irradiated by 121.6 nm photons at different temperatures. In the case of H(2)O ice, H(2)O(2) is formed at the temperatures below 60 К. In the case of H(2)O:O(2) ice, H(2)O(2) is formed in the 20–140 К range. For H(2)O:O(2) = 9:1 ice, we derived H(2)O(2) photochemical quantum yield as a function of sample irradiation temperature. The obtained data can be used for evaluation of H(2)O(2) photoproduction at the surface of astrophysical water ice bodies and inside the particles of Noctilucent Clouds in the Earth’s atmosphere.
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spelling pubmed-66848102019-08-11 H(2)O(2) photoproduction inside H(2)O and H(2)O:O(2) ices at 20–140 K Kulikov, Mikhail Yu. Feigin, Alexander M. Schrems, Otto Sci Rep Article We report the results of laboratory measurements of H(2)O(2) production inside thin (50 nm thickness) H(2)O and H(2)O:O(2) ice samples irradiated by 121.6 nm photons at different temperatures. In the case of H(2)O ice, H(2)O(2) is formed at the temperatures below 60 К. In the case of H(2)O:O(2) ice, H(2)O(2) is formed in the 20–140 К range. For H(2)O:O(2) = 9:1 ice, we derived H(2)O(2) photochemical quantum yield as a function of sample irradiation temperature. The obtained data can be used for evaluation of H(2)O(2) photoproduction at the surface of astrophysical water ice bodies and inside the particles of Noctilucent Clouds in the Earth’s atmosphere. Nature Publishing Group UK 2019-08-06 /pmc/articles/PMC6684810/ /pubmed/31388066 http://dx.doi.org/10.1038/s41598-019-47915-w Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Kulikov, Mikhail Yu.
Feigin, Alexander M.
Schrems, Otto
H(2)O(2) photoproduction inside H(2)O and H(2)O:O(2) ices at 20–140 K
title H(2)O(2) photoproduction inside H(2)O and H(2)O:O(2) ices at 20–140 K
title_full H(2)O(2) photoproduction inside H(2)O and H(2)O:O(2) ices at 20–140 K
title_fullStr H(2)O(2) photoproduction inside H(2)O and H(2)O:O(2) ices at 20–140 K
title_full_unstemmed H(2)O(2) photoproduction inside H(2)O and H(2)O:O(2) ices at 20–140 K
title_short H(2)O(2) photoproduction inside H(2)O and H(2)O:O(2) ices at 20–140 K
title_sort h(2)o(2) photoproduction inside h(2)o and h(2)o:o(2) ices at 20–140 k
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6684810/
https://www.ncbi.nlm.nih.gov/pubmed/31388066
http://dx.doi.org/10.1038/s41598-019-47915-w
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