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Catalytic Au(i)/Au(iii) arylation with the hemilabile MeDalphos ligand: unusual selectivity for electron-rich iodoarenes and efficient application to indoles

The ability of the hemilabile (P,N) MeDalphos ligand to trigger oxidative addition of iodoarenes to gold has been thoroughly studied. Competition experiments and Hammett correlations substantiate a clear preference of gold for electron-enriched substrates both in stoichiometric oxidative addition re...

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Detalles Bibliográficos
Autores principales:	Rodriguez, Jessica, Zeineddine, Abdallah, Sosa Carrizo, E. Daiann, Miqueu, Karinne, Saffon-Merceron, Nathalie, Amgoune, Abderrahmane, Bourissou, Didier
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6685352/ https://www.ncbi.nlm.nih.gov/pubmed/31588286 http://dx.doi.org/10.1039/c9sc01954e

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