Substituent-controlled, mild oxidative fluorination of iodoarenes: synthesis and structural study of aryl I(iii)- and I(v)-fluorides

We report a mild approach to the synthesis of difluoro(aryl)-λ(3)-iodanes (aryl-IF(2) compounds) and tetrafluoro(aryl)-λ(5)-iodanes (aryl-IF(4) compounds) using trichloroisocyanuric acid (TCICA) and potassium fluoride (KF). Under these reaction conditions, selective access to either the I(iii)- or I...

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Detalles Bibliográficos
Autores principales: Häfliger, Joel, Pitts, Cody Ross, Bornemann, Dustin, Käser, Roland, Santschi, Nico, Charpentier, Julie, Otth, Elisabeth, Trapp, Nils, Verel, René, Lüthi, Hans Peter, Togni, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6685355/
https://www.ncbi.nlm.nih.gov/pubmed/31588294
http://dx.doi.org/10.1039/c9sc02162k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6685355/
https://www.ncbi.nlm.nih.gov/pubmed/31588294
http://dx.doi.org/10.1039/c9sc02162k

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