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Photocarboxylation of Benzylic C–H Bonds

[Image: see text] The carboxylation of sp(3)-hybridized C–H bonds with CO(2) is a challenging transformation. Herein, we report a visible-light-mediated carboxylation of benzylic C–H bonds with CO(2) into 2-arylpropionic acids under metal-free conditions. Photo-oxidized triisopropylsilanethiol was u...

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Detalles Bibliográficos
Autores principales: Meng, Qing-Yuan, Schirmer, Tobias E., Berger, Anna Lucia, Donabauer, Karsten, König, Burkhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6686948/
https://www.ncbi.nlm.nih.gov/pubmed/31280561
http://dx.doi.org/10.1021/jacs.9b05360