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Photocarboxylation of Benzylic C–H Bonds
[Image: see text] The carboxylation of sp(3)-hybridized C–H bonds with CO(2) is a challenging transformation. Herein, we report a visible-light-mediated carboxylation of benzylic C–H bonds with CO(2) into 2-arylpropionic acids under metal-free conditions. Photo-oxidized triisopropylsilanethiol was u...
Autores principales: | Meng, Qing-Yuan, Schirmer, Tobias E., Berger, Anna Lucia, Donabauer, Karsten, König, Burkhard |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2019
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6686948/ https://www.ncbi.nlm.nih.gov/pubmed/31280561 http://dx.doi.org/10.1021/jacs.9b05360 |
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