Parallels between Metal‐Ligand Cooperativity and Frustrated Lewis Pairs

Metal ligand cooperativity (MLC) and frustrated Lewis pair (FLP) chemistry both feature the cooperative action of a Lewis acidic and a Lewis basic site on a substrate. A lot of work has been carried out in the field of FLPs to prevent Lewis adduct formation, which often reduces the FLP reactivity. P...

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Detalles Bibliográficos
Autores principales: Habraken, Evi R. M., Jupp, Andrew R., Brands, Maria B., Nieger, Martin, Ehlers, Andreas W., Slootweg, J. Chris
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6687039/
https://www.ncbi.nlm.nih.gov/pubmed/31423108
http://dx.doi.org/10.1002/ejic.201900169
Descripción
Sumario:Metal ligand cooperativity (MLC) and frustrated Lewis pair (FLP) chemistry both feature the cooperative action of a Lewis acidic and a Lewis basic site on a substrate. A lot of work has been carried out in the field of FLPs to prevent Lewis adduct formation, which often reduces the FLP reactivity. Parallels are drawn between the two systems by looking at their reactivity with CO(2), and we explore the role of steric bulk in preventing dimer formation in MLC systems.

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