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Stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency

Solution-processable perovskites show highly emissive and good charge transport, making them attractive for low-cost light-emitting diodes (LEDs) with high energy conversion efficiencies. Despite recent advances in device efficiency, the stability of perovskite LEDs is still a major obstacle. Here,...

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Detalles Bibliográficos
Autores principales: Miao, Yanfeng, Ke, You, Wang, Nana, Zou, Wei, Xu, Mengmeng, Cao, Yu, Sun, Yan, Yang, Rong, Wang, Ying, Tong, Yunfang, Xu, Wenjie, Zhang, Liangdong, Li, Renzhi, Li, Jing, He, Haiping, Jin, Yizheng, Gao, Feng, Huang, Wei, Wang, Jianpu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6689020/
https://www.ncbi.nlm.nih.gov/pubmed/31399580
http://dx.doi.org/10.1038/s41467-019-11567-1
Descripción
Sumario:Solution-processable perovskites show highly emissive and good charge transport, making them attractive for low-cost light-emitting diodes (LEDs) with high energy conversion efficiencies. Despite recent advances in device efficiency, the stability of perovskite LEDs is still a major obstacle. Here, we demonstrate stable and bright perovskite LEDs with high energy conversion efficiencies by optimizing formamidinium lead iodide films. Our LEDs show an energy conversion efficiency of 10.7%, and an external quantum efficiency of 14.2% without outcoupling enhancement through controlling the concentration of the precursor solutions. The device shows low efficiency droop, i.e. 8.3% energy conversion efficiency and 14.0% external quantum efficiency at a current density of 300 mA cm(−2), making the device more efficient than state-of-the-art organic and quantum-dot LEDs at high current densities. Furthermore, the half-lifetime of device with benzylamine treatment is 23.7 hr under a current density of 100 mA cm(−2), comparable to the lifetime of near-infrared organic LEDs.