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Stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency

Solution-processable perovskites show highly emissive and good charge transport, making them attractive for low-cost light-emitting diodes (LEDs) with high energy conversion efficiencies. Despite recent advances in device efficiency, the stability of perovskite LEDs is still a major obstacle. Here,...

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Autores principales: Miao, Yanfeng, Ke, You, Wang, Nana, Zou, Wei, Xu, Mengmeng, Cao, Yu, Sun, Yan, Yang, Rong, Wang, Ying, Tong, Yunfang, Xu, Wenjie, Zhang, Liangdong, Li, Renzhi, Li, Jing, He, Haiping, Jin, Yizheng, Gao, Feng, Huang, Wei, Wang, Jianpu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6689020/
https://www.ncbi.nlm.nih.gov/pubmed/31399580
http://dx.doi.org/10.1038/s41467-019-11567-1
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author Miao, Yanfeng
Ke, You
Wang, Nana
Zou, Wei
Xu, Mengmeng
Cao, Yu
Sun, Yan
Yang, Rong
Wang, Ying
Tong, Yunfang
Xu, Wenjie
Zhang, Liangdong
Li, Renzhi
Li, Jing
He, Haiping
Jin, Yizheng
Gao, Feng
Huang, Wei
Wang, Jianpu
author_facet Miao, Yanfeng
Ke, You
Wang, Nana
Zou, Wei
Xu, Mengmeng
Cao, Yu
Sun, Yan
Yang, Rong
Wang, Ying
Tong, Yunfang
Xu, Wenjie
Zhang, Liangdong
Li, Renzhi
Li, Jing
He, Haiping
Jin, Yizheng
Gao, Feng
Huang, Wei
Wang, Jianpu
author_sort Miao, Yanfeng
collection PubMed
description Solution-processable perovskites show highly emissive and good charge transport, making them attractive for low-cost light-emitting diodes (LEDs) with high energy conversion efficiencies. Despite recent advances in device efficiency, the stability of perovskite LEDs is still a major obstacle. Here, we demonstrate stable and bright perovskite LEDs with high energy conversion efficiencies by optimizing formamidinium lead iodide films. Our LEDs show an energy conversion efficiency of 10.7%, and an external quantum efficiency of 14.2% without outcoupling enhancement through controlling the concentration of the precursor solutions. The device shows low efficiency droop, i.e. 8.3% energy conversion efficiency and 14.0% external quantum efficiency at a current density of 300 mA cm(−2), making the device more efficient than state-of-the-art organic and quantum-dot LEDs at high current densities. Furthermore, the half-lifetime of device with benzylamine treatment is 23.7 hr under a current density of 100 mA cm(−2), comparable to the lifetime of near-infrared organic LEDs.
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spelling pubmed-66890202019-08-12 Stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency Miao, Yanfeng Ke, You Wang, Nana Zou, Wei Xu, Mengmeng Cao, Yu Sun, Yan Yang, Rong Wang, Ying Tong, Yunfang Xu, Wenjie Zhang, Liangdong Li, Renzhi Li, Jing He, Haiping Jin, Yizheng Gao, Feng Huang, Wei Wang, Jianpu Nat Commun Article Solution-processable perovskites show highly emissive and good charge transport, making them attractive for low-cost light-emitting diodes (LEDs) with high energy conversion efficiencies. Despite recent advances in device efficiency, the stability of perovskite LEDs is still a major obstacle. Here, we demonstrate stable and bright perovskite LEDs with high energy conversion efficiencies by optimizing formamidinium lead iodide films. Our LEDs show an energy conversion efficiency of 10.7%, and an external quantum efficiency of 14.2% without outcoupling enhancement through controlling the concentration of the precursor solutions. The device shows low efficiency droop, i.e. 8.3% energy conversion efficiency and 14.0% external quantum efficiency at a current density of 300 mA cm(−2), making the device more efficient than state-of-the-art organic and quantum-dot LEDs at high current densities. Furthermore, the half-lifetime of device with benzylamine treatment is 23.7 hr under a current density of 100 mA cm(−2), comparable to the lifetime of near-infrared organic LEDs. Nature Publishing Group UK 2019-08-09 /pmc/articles/PMC6689020/ /pubmed/31399580 http://dx.doi.org/10.1038/s41467-019-11567-1 Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Miao, Yanfeng
Ke, You
Wang, Nana
Zou, Wei
Xu, Mengmeng
Cao, Yu
Sun, Yan
Yang, Rong
Wang, Ying
Tong, Yunfang
Xu, Wenjie
Zhang, Liangdong
Li, Renzhi
Li, Jing
He, Haiping
Jin, Yizheng
Gao, Feng
Huang, Wei
Wang, Jianpu
Stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency
title Stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency
title_full Stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency
title_fullStr Stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency
title_full_unstemmed Stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency
title_short Stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency
title_sort stable and bright formamidinium-based perovskite light-emitting diodes with high energy conversion efficiency
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6689020/
https://www.ncbi.nlm.nih.gov/pubmed/31399580
http://dx.doi.org/10.1038/s41467-019-11567-1
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