Two isomers of [1-benzyl-4-(pyridin-2-yl-κN)-1H-1,2,3-triazole-κN (3)]di­chlorido­bis­(dimethyl sulfoxide-κS)ruthenium(II)

The structures of two isomers of the title compound, [RuCl(2)(C(14)H(12)N(4))(C(2)H(6)OS)(2)], 2 and 3, are reported. Isomers 2 and 3 are produced by reaction of the pyridyl­triazole ligand 1-benzyl-4-(pyridin-2-yl)-1H-1,2,3-triazole (bpt) (1) with fac-[RuCl(2)(DMSO-S)(3)(DMSO-O)]. Reaction in aceto...

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Detalles Bibliográficos
Autores principales: Khamespanah, Fatemeh, Maverick, Andrew W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690446/
https://www.ncbi.nlm.nih.gov/pubmed/31417774
http://dx.doi.org/10.1107/S2056989019008375
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author Khamespanah, Fatemeh
Maverick, Andrew W.
author_facet Khamespanah, Fatemeh
Maverick, Andrew W.
author_sort Khamespanah, Fatemeh
collection PubMed
description The structures of two isomers of the title compound, [RuCl(2)(C(14)H(12)N(4))(C(2)H(6)OS)(2)], 2 and 3, are reported. Isomers 2 and 3 are produced by reaction of the pyridyl­triazole ligand 1-benzyl-4-(pyridin-2-yl)-1H-1,2,3-triazole (bpt) (1) with fac-[RuCl(2)(DMSO-S)(3)(DMSO-O)]. Reaction in acetone produces ca 95% 2, which is the OC-6-14 isomer, with cis DMSO and trans chlorido ligands, and 5% 3 (the OC-6-32 isomer, with cis DMSO and cis chlorido ligands, and the pyridyl moiety of bpt trans to DMSO). Reaction in refluxing toluene initially forms 2, which slowly isomerizes to 3.
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spelling pubmed-66904462019-08-15 Two isomers of [1-benzyl-4-(pyridin-2-yl-κN)-1H-1,2,3-triazole-κN (3)]di­chlorido­bis­(dimethyl sulfoxide-κS)ruthenium(II) Khamespanah, Fatemeh Maverick, Andrew W. Acta Crystallogr E Crystallogr Commun Research Communications The structures of two isomers of the title compound, [RuCl(2)(C(14)H(12)N(4))(C(2)H(6)OS)(2)], 2 and 3, are reported. Isomers 2 and 3 are produced by reaction of the pyridyl­triazole ligand 1-benzyl-4-(pyridin-2-yl)-1H-1,2,3-triazole (bpt) (1) with fac-[RuCl(2)(DMSO-S)(3)(DMSO-O)]. Reaction in acetone produces ca 95% 2, which is the OC-6-14 isomer, with cis DMSO and trans chlorido ligands, and 5% 3 (the OC-6-32 isomer, with cis DMSO and cis chlorido ligands, and the pyridyl moiety of bpt trans to DMSO). Reaction in refluxing toluene initially forms 2, which slowly isomerizes to 3. International Union of Crystallography 2019-07-04 /pmc/articles/PMC6690446/ /pubmed/31417774 http://dx.doi.org/10.1107/S2056989019008375 Text en © Khamespanah and Maverick 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Khamespanah, Fatemeh
Maverick, Andrew W.
Two isomers of [1-benzyl-4-(pyridin-2-yl-κN)-1H-1,2,3-triazole-κN (3)]di­chlorido­bis­(dimethyl sulfoxide-κS)ruthenium(II)
title Two isomers of [1-benzyl-4-(pyridin-2-yl-κN)-1H-1,2,3-triazole-κN (3)]di­chlorido­bis­(dimethyl sulfoxide-κS)ruthenium(II)
title_full Two isomers of [1-benzyl-4-(pyridin-2-yl-κN)-1H-1,2,3-triazole-κN (3)]di­chlorido­bis­(dimethyl sulfoxide-κS)ruthenium(II)
title_fullStr Two isomers of [1-benzyl-4-(pyridin-2-yl-κN)-1H-1,2,3-triazole-κN (3)]di­chlorido­bis­(dimethyl sulfoxide-κS)ruthenium(II)
title_full_unstemmed Two isomers of [1-benzyl-4-(pyridin-2-yl-κN)-1H-1,2,3-triazole-κN (3)]di­chlorido­bis­(dimethyl sulfoxide-κS)ruthenium(II)
title_short Two isomers of [1-benzyl-4-(pyridin-2-yl-κN)-1H-1,2,3-triazole-κN (3)]di­chlorido­bis­(dimethyl sulfoxide-κS)ruthenium(II)
title_sort two isomers of [1-benzyl-4-(pyridin-2-yl-κn)-1h-1,2,3-triazole-κn (3)]di­chlorido­bis­(dimethyl sulfoxide-κs)ruthenium(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690446/
https://www.ncbi.nlm.nih.gov/pubmed/31417774
http://dx.doi.org/10.1107/S2056989019008375
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