(E)-6,6′-(Diazene-1,2-di­yl)bis­(1,10-phenanthrolin-5-ol) tri­chloro­methane disolvate: a superconjugated ligand

Phenanthroline ligands are important metal-binding mol­ecules which have been extensively researched for applications in both material science and medicinal chemistry. Azo­benzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E...

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Autores principales: Ahmed, Muhib, Devereux, Michael, McKee, Vickie, McCann, Malachy, Rooney, A. Denise
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690457/
https://www.ncbi.nlm.nih.gov/pubmed/31417796
http://dx.doi.org/10.1107/S205698901900954X
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author Ahmed, Muhib
Devereux, Michael
McKee, Vickie
McCann, Malachy
Rooney, A. Denise
author_facet Ahmed, Muhib
Devereux, Michael
McKee, Vickie
McCann, Malachy
Rooney, A. Denise
author_sort Ahmed, Muhib
collection PubMed
description Phenanthroline ligands are important metal-binding mol­ecules which have been extensively researched for applications in both material science and medicinal chemistry. Azo­benzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E and Z forms and so could have applications in optical memory and logic devices or as mol­ecular machines. Herein we report the formation and crystal structure of a highly unusual novel diazo-diphenanthroline compound, C(24)H(14)N(6)O(2)·2CHCl(3).
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spelling pubmed-66904572019-08-15 (E)-6,6′-(Diazene-1,2-di­yl)bis­(1,10-phenanthrolin-5-ol) tri­chloro­methane disolvate: a superconjugated ligand Ahmed, Muhib Devereux, Michael McKee, Vickie McCann, Malachy Rooney, A. Denise Acta Crystallogr E Crystallogr Commun Research Communications Phenanthroline ligands are important metal-binding mol­ecules which have been extensively researched for applications in both material science and medicinal chemistry. Azo­benzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E and Z forms and so could have applications in optical memory and logic devices or as mol­ecular machines. Herein we report the formation and crystal structure of a highly unusual novel diazo-diphenanthroline compound, C(24)H(14)N(6)O(2)·2CHCl(3). International Union of Crystallography 2019-07-23 /pmc/articles/PMC6690457/ /pubmed/31417796 http://dx.doi.org/10.1107/S205698901900954X Text en © Ahmed et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Ahmed, Muhib
Devereux, Michael
McKee, Vickie
McCann, Malachy
Rooney, A. Denise
(E)-6,6′-(Diazene-1,2-di­yl)bis­(1,10-phenanthrolin-5-ol) tri­chloro­methane disolvate: a superconjugated ligand
title (E)-6,6′-(Diazene-1,2-di­yl)bis­(1,10-phenanthrolin-5-ol) tri­chloro­methane disolvate: a superconjugated ligand
title_full (E)-6,6′-(Diazene-1,2-di­yl)bis­(1,10-phenanthrolin-5-ol) tri­chloro­methane disolvate: a superconjugated ligand
title_fullStr (E)-6,6′-(Diazene-1,2-di­yl)bis­(1,10-phenanthrolin-5-ol) tri­chloro­methane disolvate: a superconjugated ligand
title_full_unstemmed (E)-6,6′-(Diazene-1,2-di­yl)bis­(1,10-phenanthrolin-5-ol) tri­chloro­methane disolvate: a superconjugated ligand
title_short (E)-6,6′-(Diazene-1,2-di­yl)bis­(1,10-phenanthrolin-5-ol) tri­chloro­methane disolvate: a superconjugated ligand
title_sort (e)-6,6′-(diazene-1,2-di­yl)bis­(1,10-phenanthrolin-5-ol) tri­chloro­methane disolvate: a superconjugated ligand
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690457/
https://www.ncbi.nlm.nih.gov/pubmed/31417796
http://dx.doi.org/10.1107/S205698901900954X
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