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Crystal structure of (15,20-bis­(2,3,4,5,6-penta­fluoro­phen­yl)-5,10-{(pyridine-3,5-di­yl)bis­[(sulfane­diyl­methyl­ene)[1,1′-biphen­yl]-4′,2-di­yl]}porph­yrin­ato)nickel(II) di­chloro­methane x-solvate (x > 1/2) showing a rare CN5 coordination

The crystal structure of the title compound, [Ni(C(63)H(31)F(10)N(5)S(2))]·xCH(2)Cl(2) (x > 1/2), consists of Ni–porphyrin complexes that are located in general positions and di­chloro­methane solvent mol­ecules that are disordered around centers of inversion. The Ni(II) ions are in a square-pyra...

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Detalles Bibliográficos
Autores principales: Gutzeit, Florian, Näther, Christian, Herges, Rainer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690462/
https://www.ncbi.nlm.nih.gov/pubmed/31417788
http://dx.doi.org/10.1107/S2056989019009836