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Crystal structure of (15,20-bis(2,3,4,5,6-pentafluorophenyl)-5,10-{(pyridine-3,5-diyl)bis[(sulfanediylmethylene)[1,1′-biphenyl]-4′,2-diyl]}porphyrinato)nickel(II) dichloromethane x-solvate (x > 1/2) showing a rare CN5 coordination
The crystal structure of the title compound, [Ni(C(63)H(31)F(10)N(5)S(2))]·xCH(2)Cl(2) (x > 1/2), consists of Ni–porphyrin complexes that are located in general positions and dichloromethane solvent molecules that are disordered around centers of inversion. The Ni(II) ions are in a square-pyra...
Autores principales: | Gutzeit, Florian, Näther, Christian, Herges, Rainer |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690462/ https://www.ncbi.nlm.nih.gov/pubmed/31417788 http://dx.doi.org/10.1107/S2056989019009836 |
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