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Crystal structure of bis[dihydrobis(pyrazol-1-yl)borato-κ(2) N (2),N (2′)](1,10-phenanthroline-κ(2) N,N′)zinc(II)
The asymmetric unit of the title compound, [Zn(C(6)H(8)N(4)B)(2)(C(12)H(8)N(2))], comprises one half of a Zn(II) cation (site symmetry 2), one dihydrobis(pyrazol-1-yl)borate ligand in a general position, and one half of a phenanthroline ligand, the other half being completed by twofold rotation s...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690474/ https://www.ncbi.nlm.nih.gov/pubmed/31417775 http://dx.doi.org/10.1107/S2056989019009289 |
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author | Ossinger, Sascha Näther, Christian Tuczek, Felix |
author_facet | Ossinger, Sascha Näther, Christian Tuczek, Felix |
author_sort | Ossinger, Sascha |
collection | PubMed |
description | The asymmetric unit of the title compound, [Zn(C(6)H(8)N(4)B)(2)(C(12)H(8)N(2))], comprises one half of a Zn(II) cation (site symmetry 2), one dihydrobis(pyrazol-1-yl)borate ligand in a general position, and one half of a phenanthroline ligand, the other half being completed by twofold rotation symmetry. The Zn(II) cation is coordinated in form of a slightly distorted octahedron by the N atoms of a phenanthroline ligand and by two pairs of N atoms of symmetry-related dihydrobis(pyrazol-1-yl)borate ligands. The discrete complexes are arranged into columns that elongate in the c-axis direction with a parallel alignment of the phenanthroline ligands, indicating weak π–π interactions. |
format | Online Article Text |
id | pubmed-6690474 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-66904742019-08-15 Crystal structure of bis[dihydrobis(pyrazol-1-yl)borato-κ(2) N (2),N (2′)](1,10-phenanthroline-κ(2) N,N′)zinc(II) Ossinger, Sascha Näther, Christian Tuczek, Felix Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, [Zn(C(6)H(8)N(4)B)(2)(C(12)H(8)N(2))], comprises one half of a Zn(II) cation (site symmetry 2), one dihydrobis(pyrazol-1-yl)borate ligand in a general position, and one half of a phenanthroline ligand, the other half being completed by twofold rotation symmetry. The Zn(II) cation is coordinated in form of a slightly distorted octahedron by the N atoms of a phenanthroline ligand and by two pairs of N atoms of symmetry-related dihydrobis(pyrazol-1-yl)borate ligands. The discrete complexes are arranged into columns that elongate in the c-axis direction with a parallel alignment of the phenanthroline ligands, indicating weak π–π interactions. International Union of Crystallography 2019-07-04 /pmc/articles/PMC6690474/ /pubmed/31417775 http://dx.doi.org/10.1107/S2056989019009289 Text en © Ossinger et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Ossinger, Sascha Näther, Christian Tuczek, Felix Crystal structure of bis[dihydrobis(pyrazol-1-yl)borato-κ(2) N (2),N (2′)](1,10-phenanthroline-κ(2) N,N′)zinc(II) |
title | Crystal structure of bis[dihydrobis(pyrazol-1-yl)borato-κ(2)
N
(2),N
(2′)](1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_full | Crystal structure of bis[dihydrobis(pyrazol-1-yl)borato-κ(2)
N
(2),N
(2′)](1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_fullStr | Crystal structure of bis[dihydrobis(pyrazol-1-yl)borato-κ(2)
N
(2),N
(2′)](1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_full_unstemmed | Crystal structure of bis[dihydrobis(pyrazol-1-yl)borato-κ(2)
N
(2),N
(2′)](1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_short | Crystal structure of bis[dihydrobis(pyrazol-1-yl)borato-κ(2)
N
(2),N
(2′)](1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_sort | crystal structure of bis[dihydrobis(pyrazol-1-yl)borato-κ(2)
n
(2),n
(2′)](1,10-phenanthroline-κ(2)
n,n′)zinc(ii) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6690474/ https://www.ncbi.nlm.nih.gov/pubmed/31417775 http://dx.doi.org/10.1107/S2056989019009289 |
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