Copper-catalyzed dehydrogenative γ-C(sp(3))-H amination of saturated ketones for synthesis of polysubstituted anilines

Metal-catalyzed β-C-H functionalization of saturated carbonyls via dehydrogenative desaturation proved to be a powerful tool for simplifying synthesis of valuable β-substituted carbonyls. Here, we report a copper-catalyzed dehydrogenative γ-C(sp(3))-H amination of saturated ketones that initiates th...

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Detalles Bibliográficos
Autores principales: Hu, Rong, Chen, Fa-Jie, Zhang, Xiaofeng, Zhang, Min, Su, Weiping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6695438/
https://www.ncbi.nlm.nih.gov/pubmed/31417081
http://dx.doi.org/10.1038/s41467-019-11624-9

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6695438/
https://www.ncbi.nlm.nih.gov/pubmed/31417081
http://dx.doi.org/10.1038/s41467-019-11624-9

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