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Evolution of Oxygen–Ion and Proton Conductivity in Ca-Doped Ln(2)Zr(2)O(7) (Ln = Sm, Gd), Located Near Pyrochlore–Fluorite Phase Boundary
Sm(2−x)Ca(x)Zr(2)O(7−x/2) (x = 0, 0.05, 0.1) and Gd(2−x)Ca(x)Zr(2)O(7−x/2) (x = 0.05, 0.1) mixed oxides in a pyrochlore–fluorite morphotropic phase region were prepared via the mechanical activation of oxide mixtures, followed by annealing at 1600 °C. The structure of the solid solutions was studied...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6696096/ https://www.ncbi.nlm.nih.gov/pubmed/31374863 http://dx.doi.org/10.3390/ma12152452 |