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Synthesis, X-ray Crystal Structure, and Photochromism of a Sandwich-Type Mono-Aluminum Complex Composed of Two Tri-Lacunary α-Dawson-Type Polyoxotungstates
The synthesis and molecular structure of a dimeric, mono-aluminum complex composed of two tri-lacunary α-Dawson polyoxometalates, [H(14)Al(B-α-P(2)W(15)O(56))(2)](7−) (1), is described herein. The tetra-n-butylammonium salt of 1, [(n-C(4)H(9))(4)N](7)[H(14)Al(B-α-P(2)W(15)O(56))(2)] (TBA-1) was prep...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6696191/ https://www.ncbi.nlm.nih.gov/pubmed/31357405 http://dx.doi.org/10.3390/ma12152383 |