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Synergy of Sulfur/Polyacrylonitrile Composite and Gel Polymer Electrolyte Promises Heat-Resistant Lithium-Sulfur Batteries
Lithium-sulfur (Li-S) batteries with high theoretical energy density attract great research attention. Although tremendous efforts have been made, heat tolerance capability of Li-S batteries is a topic rarely touched, although it is essential for practical application. At high temperatures, the diss...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6700433/ https://www.ncbi.nlm.nih.gov/pubmed/31404832 http://dx.doi.org/10.1016/j.isci.2019.07.027 |
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author | Liu, Yu Yang, Dezhi Yan, Wenqi Huang, Qinghong Zhu, Yusong Fu, Lijun Wu, Yuping |
author_facet | Liu, Yu Yang, Dezhi Yan, Wenqi Huang, Qinghong Zhu, Yusong Fu, Lijun Wu, Yuping |
author_sort | Liu, Yu |
collection | PubMed |
description | Lithium-sulfur (Li-S) batteries with high theoretical energy density attract great research attention. Although tremendous efforts have been made, heat tolerance capability of Li-S batteries is a topic rarely touched, although it is essential for practical application. At high temperatures, the dissolution of the polysulfides is aggravated, and the safety issue becomes severe. Herein, by using sulfur/polyacrylonitrile (SPAN) composites as positive electrode materials and a gel polymer membrane with carbonate electrolyte, we successfully realized a Li-S battery with remarkable heat-resistant performance at 50°C and 60°C. The SPAN-positive materials allow the Li-S battery operated in safer carbonate-containing electrolyte. The gel polymer electrolyte enhances the charge transfer, maintains the morphology of Li metal during cycling, and suppresses the migration of the soluble polysulfides, which is also observed when SPAN is used as positive electrode material. This contribution would bring new opportunity to extend the application of lithium batteries at high temperatures. |
format | Online Article Text |
id | pubmed-6700433 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-67004332019-08-26 Synergy of Sulfur/Polyacrylonitrile Composite and Gel Polymer Electrolyte Promises Heat-Resistant Lithium-Sulfur Batteries Liu, Yu Yang, Dezhi Yan, Wenqi Huang, Qinghong Zhu, Yusong Fu, Lijun Wu, Yuping iScience Article Lithium-sulfur (Li-S) batteries with high theoretical energy density attract great research attention. Although tremendous efforts have been made, heat tolerance capability of Li-S batteries is a topic rarely touched, although it is essential for practical application. At high temperatures, the dissolution of the polysulfides is aggravated, and the safety issue becomes severe. Herein, by using sulfur/polyacrylonitrile (SPAN) composites as positive electrode materials and a gel polymer membrane with carbonate electrolyte, we successfully realized a Li-S battery with remarkable heat-resistant performance at 50°C and 60°C. The SPAN-positive materials allow the Li-S battery operated in safer carbonate-containing electrolyte. The gel polymer electrolyte enhances the charge transfer, maintains the morphology of Li metal during cycling, and suppresses the migration of the soluble polysulfides, which is also observed when SPAN is used as positive electrode material. This contribution would bring new opportunity to extend the application of lithium batteries at high temperatures. Elsevier 2019-07-20 /pmc/articles/PMC6700433/ /pubmed/31404832 http://dx.doi.org/10.1016/j.isci.2019.07.027 Text en © 2019 The Authors http://creativecommons.org/licenses/by-nc-nd/4.0/ This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Article Liu, Yu Yang, Dezhi Yan, Wenqi Huang, Qinghong Zhu, Yusong Fu, Lijun Wu, Yuping Synergy of Sulfur/Polyacrylonitrile Composite and Gel Polymer Electrolyte Promises Heat-Resistant Lithium-Sulfur Batteries |
title | Synergy of Sulfur/Polyacrylonitrile Composite and Gel Polymer Electrolyte Promises Heat-Resistant Lithium-Sulfur Batteries |
title_full | Synergy of Sulfur/Polyacrylonitrile Composite and Gel Polymer Electrolyte Promises Heat-Resistant Lithium-Sulfur Batteries |
title_fullStr | Synergy of Sulfur/Polyacrylonitrile Composite and Gel Polymer Electrolyte Promises Heat-Resistant Lithium-Sulfur Batteries |
title_full_unstemmed | Synergy of Sulfur/Polyacrylonitrile Composite and Gel Polymer Electrolyte Promises Heat-Resistant Lithium-Sulfur Batteries |
title_short | Synergy of Sulfur/Polyacrylonitrile Composite and Gel Polymer Electrolyte Promises Heat-Resistant Lithium-Sulfur Batteries |
title_sort | synergy of sulfur/polyacrylonitrile composite and gel polymer electrolyte promises heat-resistant lithium-sulfur batteries |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6700433/ https://www.ncbi.nlm.nih.gov/pubmed/31404832 http://dx.doi.org/10.1016/j.isci.2019.07.027 |
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