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Ultrasonic velocity, density, viscosity for the ternary mixture of (benzene + chloroform + cyclohexane) at different temperatures

Ultrasonic velocity (U), density (ρ), viscosity (ƞ) for the ternary mixture of benzene + chloroform + cyclohexane in the whole range of composition has been carried out at various temperatures 303.15, 308.15 and 313.15K. From the measured parameters U, ρ and ƞ, some derived parameters β, L(f), V(f),...

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Autores principales: Vanathi, V., Mullainathan, S., Nithiyanatham, S., Ramasamy, V., Palaniappan, L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6704351/
https://www.ncbi.nlm.nih.gov/pubmed/31453394
http://dx.doi.org/10.1016/j.heliyon.2019.e02203
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author Vanathi, V.
Mullainathan, S.
Nithiyanatham, S.
Ramasamy, V.
Palaniappan, L.
author_facet Vanathi, V.
Mullainathan, S.
Nithiyanatham, S.
Ramasamy, V.
Palaniappan, L.
author_sort Vanathi, V.
collection PubMed
description Ultrasonic velocity (U), density (ρ), viscosity (ƞ) for the ternary mixture of benzene + chloroform + cyclohexane in the whole range of composition has been carried out at various temperatures 303.15, 308.15 and 313.15K. From the measured parameters U, ρ and ƞ, some derived parameters β, L(f), V(f), π(i), Z, R,W with molar enthalpy (H(m)) and apparent molar volume (ɸ(v)) are also estimated. The decreasing trend of ƞ, R,W, H(m), and ɸ(v) with concentrations and other parameters are in increasing trend were observed. The trend of acoustical and physico-chemical parameters confirm the dynamics of molecules at higher temperature and the magnitude of intermolecular interactions among the constituents of the mixtures always reflects the nature of substance. The role of enthalpy and apparent molar volume has been used to determine their thermal response. The sign and magnitude of these properties are evident for the nature of interactions between component molecules.
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spelling pubmed-67043512019-08-26 Ultrasonic velocity, density, viscosity for the ternary mixture of (benzene + chloroform + cyclohexane) at different temperatures Vanathi, V. Mullainathan, S. Nithiyanatham, S. Ramasamy, V. Palaniappan, L. Heliyon Article Ultrasonic velocity (U), density (ρ), viscosity (ƞ) for the ternary mixture of benzene + chloroform + cyclohexane in the whole range of composition has been carried out at various temperatures 303.15, 308.15 and 313.15K. From the measured parameters U, ρ and ƞ, some derived parameters β, L(f), V(f), π(i), Z, R,W with molar enthalpy (H(m)) and apparent molar volume (ɸ(v)) are also estimated. The decreasing trend of ƞ, R,W, H(m), and ɸ(v) with concentrations and other parameters are in increasing trend were observed. The trend of acoustical and physico-chemical parameters confirm the dynamics of molecules at higher temperature and the magnitude of intermolecular interactions among the constituents of the mixtures always reflects the nature of substance. The role of enthalpy and apparent molar volume has been used to determine their thermal response. The sign and magnitude of these properties are evident for the nature of interactions between component molecules. Elsevier 2019-08-14 /pmc/articles/PMC6704351/ /pubmed/31453394 http://dx.doi.org/10.1016/j.heliyon.2019.e02203 Text en © 2019 Published by Elsevier Ltd. http://creativecommons.org/licenses/by-nc-nd/4.0/ This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Article
Vanathi, V.
Mullainathan, S.
Nithiyanatham, S.
Ramasamy, V.
Palaniappan, L.
Ultrasonic velocity, density, viscosity for the ternary mixture of (benzene + chloroform + cyclohexane) at different temperatures
title Ultrasonic velocity, density, viscosity for the ternary mixture of (benzene + chloroform + cyclohexane) at different temperatures
title_full Ultrasonic velocity, density, viscosity for the ternary mixture of (benzene + chloroform + cyclohexane) at different temperatures
title_fullStr Ultrasonic velocity, density, viscosity for the ternary mixture of (benzene + chloroform + cyclohexane) at different temperatures
title_full_unstemmed Ultrasonic velocity, density, viscosity for the ternary mixture of (benzene + chloroform + cyclohexane) at different temperatures
title_short Ultrasonic velocity, density, viscosity for the ternary mixture of (benzene + chloroform + cyclohexane) at different temperatures
title_sort ultrasonic velocity, density, viscosity for the ternary mixture of (benzene + chloroform + cyclohexane) at different temperatures
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6704351/
https://www.ncbi.nlm.nih.gov/pubmed/31453394
http://dx.doi.org/10.1016/j.heliyon.2019.e02203
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AT nithiyanathams ultrasonicvelocitydensityviscosityfortheternarymixtureofbenzenechloroformcyclohexaneatdifferenttemperatures
AT ramasamyv ultrasonicvelocitydensityviscosityfortheternarymixtureofbenzenechloroformcyclohexaneatdifferenttemperatures
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