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A Gallium-based Chiral Solvating Agent Enables the Use of (1)H NMR Spectroscopy to Differentiate Chiral Alcohols
In situ, direct (1)H NMR chiral analysis by using chiral solvating agents is a convenient and efficient analytical technique. Here we developed a Ga-based chiral anionic metal complex for (1)H NMR chiral analysis of alcohols. Utilizing the optimal pK(a) value, the Ga complex was able to differentiat...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Elsevier
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6704394/ https://www.ncbi.nlm.nih.gov/pubmed/31421597 http://dx.doi.org/10.1016/j.isci.2019.07.051 |