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Novel Organic–Inorganic Perovskite Compounds Having Phosphonium Groups
[Image: see text] Organic–inorganic perovskites are composed of organic cations and [PbX(6)](4–) octahedra, and the properties change depending on the type of organic cations. To identify the effect of organic cations and control the properties of the perovskite, thin films were prepared using quate...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6705203/ https://www.ncbi.nlm.nih.gov/pubmed/31460453 http://dx.doi.org/10.1021/acsomega.9b01415 |
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author | Shimizu, Shunsuke Yoshizawa-Fujita, Masahiro Takeoka, Yuko Rikukawa, Masahiro |
author_facet | Shimizu, Shunsuke Yoshizawa-Fujita, Masahiro Takeoka, Yuko Rikukawa, Masahiro |
author_sort | Shimizu, Shunsuke |
collection | PubMed |
description | [Image: see text] Organic–inorganic perovskites are composed of organic cations and [PbX(6)](4–) octahedra, and the properties change depending on the type of organic cations. To identify the effect of organic cations and control the properties of the perovskite, thin films were prepared using quaternary alkylammonium and quaternary alkylphosphonium cations, which have big steric effects. A big steric effect can generate the distortion of [PbX(6)](4–) octahedra leading to changes in properties. A thin film of a Pb-based organic–inorganic perovskite having quaternary alkylphosphonium cations was prepared for the first time. An exciton absorption was observed at a lower wavelength than other perovskites prepared from primary and quaternary ammonium salts. The perovskite with phosphonium groups was thermally stable compared with ammonium groups. |
format | Online Article Text |
id | pubmed-6705203 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-67052032019-08-27 Novel Organic–Inorganic Perovskite Compounds Having Phosphonium Groups Shimizu, Shunsuke Yoshizawa-Fujita, Masahiro Takeoka, Yuko Rikukawa, Masahiro ACS Omega [Image: see text] Organic–inorganic perovskites are composed of organic cations and [PbX(6)](4–) octahedra, and the properties change depending on the type of organic cations. To identify the effect of organic cations and control the properties of the perovskite, thin films were prepared using quaternary alkylammonium and quaternary alkylphosphonium cations, which have big steric effects. A big steric effect can generate the distortion of [PbX(6)](4–) octahedra leading to changes in properties. A thin film of a Pb-based organic–inorganic perovskite having quaternary alkylphosphonium cations was prepared for the first time. An exciton absorption was observed at a lower wavelength than other perovskites prepared from primary and quaternary ammonium salts. The perovskite with phosphonium groups was thermally stable compared with ammonium groups. American Chemical Society 2019-08-06 /pmc/articles/PMC6705203/ /pubmed/31460453 http://dx.doi.org/10.1021/acsomega.9b01415 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Shimizu, Shunsuke Yoshizawa-Fujita, Masahiro Takeoka, Yuko Rikukawa, Masahiro Novel Organic–Inorganic Perovskite Compounds Having Phosphonium Groups |
title | Novel Organic–Inorganic Perovskite Compounds
Having Phosphonium Groups |
title_full | Novel Organic–Inorganic Perovskite Compounds
Having Phosphonium Groups |
title_fullStr | Novel Organic–Inorganic Perovskite Compounds
Having Phosphonium Groups |
title_full_unstemmed | Novel Organic–Inorganic Perovskite Compounds
Having Phosphonium Groups |
title_short | Novel Organic–Inorganic Perovskite Compounds
Having Phosphonium Groups |
title_sort | novel organic–inorganic perovskite compounds
having phosphonium groups |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6705203/ https://www.ncbi.nlm.nih.gov/pubmed/31460453 http://dx.doi.org/10.1021/acsomega.9b01415 |
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