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Spinning Approach for Cellulose Fiber Yarn Using a Deep Eutectic Solvent and an Inclined Channel

[Image: see text] We developed a spinning approach for a dope produced by treating softwood pulp with a deep eutectic solvent (DES). The DES enables formation of a sufficiently viscous spinnable gel-like suspension of fibers, which solidifies upon the removal of the DES. This solidification, however...

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Autores principales: Klar, Ville, Orelma, Hannes, Rautkoski, Hille, Kuosmanen, Petri, Harlin, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6709781/
https://www.ncbi.nlm.nih.gov/pubmed/31459203
http://dx.doi.org/10.1021/acsomega.8b01458
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author Klar, Ville
Orelma, Hannes
Rautkoski, Hille
Kuosmanen, Petri
Harlin, Ali
author_facet Klar, Ville
Orelma, Hannes
Rautkoski, Hille
Kuosmanen, Petri
Harlin, Ali
author_sort Klar, Ville
collection PubMed
description [Image: see text] We developed a spinning approach for a dope produced by treating softwood pulp with a deep eutectic solvent (DES). The DES enables formation of a sufficiently viscous spinnable gel-like suspension of fibers, which solidifies upon the removal of the DES. This solidification, however, requires a longer time compared to most conventional wet spinning processes. Consequently, the continuity of the spinning process has been constrained in previous work. Moreover, the ability to draw the incipient yarn to increase orientation has been limited. Here we present a continuous spinning approach where the fiber yarn properties and processability can be improved using an inclined channel. A combination of an air gap and an inclined ethanol stream transports and draws the incipient fiber yarn during spinning. The influence of syringe tip diameter, angle of the channel, ethanol flow rate, and twisting were studied experimentally. The improvements in the spinning process resulted in an increase in load bearing capability and ability to reduce the linear density of the fiber yarn.
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spelling pubmed-67097812019-08-27 Spinning Approach for Cellulose Fiber Yarn Using a Deep Eutectic Solvent and an Inclined Channel Klar, Ville Orelma, Hannes Rautkoski, Hille Kuosmanen, Petri Harlin, Ali ACS Omega [Image: see text] We developed a spinning approach for a dope produced by treating softwood pulp with a deep eutectic solvent (DES). The DES enables formation of a sufficiently viscous spinnable gel-like suspension of fibers, which solidifies upon the removal of the DES. This solidification, however, requires a longer time compared to most conventional wet spinning processes. Consequently, the continuity of the spinning process has been constrained in previous work. Moreover, the ability to draw the incipient yarn to increase orientation has been limited. Here we present a continuous spinning approach where the fiber yarn properties and processability can be improved using an inclined channel. A combination of an air gap and an inclined ethanol stream transports and draws the incipient fiber yarn during spinning. The influence of syringe tip diameter, angle of the channel, ethanol flow rate, and twisting were studied experimentally. The improvements in the spinning process resulted in an increase in load bearing capability and ability to reduce the linear density of the fiber yarn. American Chemical Society 2018-09-10 /pmc/articles/PMC6709781/ /pubmed/31459203 http://dx.doi.org/10.1021/acsomega.8b01458 Text en Copyright © 2018 American Chemical Society
spellingShingle Klar, Ville
Orelma, Hannes
Rautkoski, Hille
Kuosmanen, Petri
Harlin, Ali
Spinning Approach for Cellulose Fiber Yarn Using a Deep Eutectic Solvent and an Inclined Channel
title Spinning Approach for Cellulose Fiber Yarn Using a Deep Eutectic Solvent and an Inclined Channel
title_full Spinning Approach for Cellulose Fiber Yarn Using a Deep Eutectic Solvent and an Inclined Channel
title_fullStr Spinning Approach for Cellulose Fiber Yarn Using a Deep Eutectic Solvent and an Inclined Channel
title_full_unstemmed Spinning Approach for Cellulose Fiber Yarn Using a Deep Eutectic Solvent and an Inclined Channel
title_short Spinning Approach for Cellulose Fiber Yarn Using a Deep Eutectic Solvent and an Inclined Channel
title_sort spinning approach for cellulose fiber yarn using a deep eutectic solvent and an inclined channel
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6709781/
https://www.ncbi.nlm.nih.gov/pubmed/31459203
http://dx.doi.org/10.1021/acsomega.8b01458
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