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Catalytic hydrogen atom transfer from hydrosilanes to vinylarenes for hydrosilylation and polymerization
Because of the importance of hydrogen atom transfer (HAT) in biology and chemistry, there is increased interest in new strategies to perform HAT in a sustainable manner. Here, we describe a sustainable, net redox-neutral HAT process involving hydrosilanes and alkali metal Lewis base catalysts — elim...
| Autores principales: | , , , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6711469/ https://www.ncbi.nlm.nih.gov/pubmed/31460492 http://dx.doi.org/10.1038/s41929-018-0217-z |