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Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B–B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystal...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6713863/ https://www.ncbi.nlm.nih.gov/pubmed/31489159 http://dx.doi.org/10.1039/c9sc02544h |
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author | Brückner, Tobias Dewhurst, Rian D. Dellermann, Theresa Müller, Marcel Braunschweig, Holger |
author_facet | Brückner, Tobias Dewhurst, Rian D. Dellermann, Theresa Müller, Marcel Braunschweig, Holger |
author_sort | Brückner, Tobias |
collection | PubMed |
description | A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B–B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystallinity and extreme insolubility in a wide range of solvents. |
format | Online Article Text |
id | pubmed-6713863 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-67138632019-09-05 Mild synthesis of diboryldiborenes by diboration of B–B triple bonds Brückner, Tobias Dewhurst, Rian D. Dellermann, Theresa Müller, Marcel Braunschweig, Holger Chem Sci Chemistry A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B–B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystallinity and extreme insolubility in a wide range of solvents. Royal Society of Chemistry 2019-06-11 /pmc/articles/PMC6713863/ /pubmed/31489159 http://dx.doi.org/10.1039/c9sc02544h Text en This journal is © The Royal Society of Chemistry 2019 https://creativecommons.org/licenses/by-nc/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0) |
spellingShingle | Chemistry Brückner, Tobias Dewhurst, Rian D. Dellermann, Theresa Müller, Marcel Braunschweig, Holger Mild synthesis of diboryldiborenes by diboration of B–B triple bonds |
title | Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
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title_full | Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
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title_fullStr | Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
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title_full_unstemmed | Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
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title_short | Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
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title_sort | mild synthesis of diboryldiborenes by diboration of b–b triple bonds |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6713863/ https://www.ncbi.nlm.nih.gov/pubmed/31489159 http://dx.doi.org/10.1039/c9sc02544h |
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