Mild synthesis of diboryldiborenes by diboration of B–B triple bonds

A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B–B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystal...

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Autores principales: Brückner, Tobias, Dewhurst, Rian D., Dellermann, Theresa, Müller, Marcel, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6713863/
https://www.ncbi.nlm.nih.gov/pubmed/31489159
http://dx.doi.org/10.1039/c9sc02544h
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author Brückner, Tobias
Dewhurst, Rian D.
Dellermann, Theresa
Müller, Marcel
Braunschweig, Holger
author_facet Brückner, Tobias
Dewhurst, Rian D.
Dellermann, Theresa
Müller, Marcel
Braunschweig, Holger
author_sort Brückner, Tobias
collection PubMed
description A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B–B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystallinity and extreme insolubility in a wide range of solvents.
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spelling pubmed-67138632019-09-05 Mild synthesis of diboryldiborenes by diboration of B–B triple bonds Brückner, Tobias Dewhurst, Rian D. Dellermann, Theresa Müller, Marcel Braunschweig, Holger Chem Sci Chemistry A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B–B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystallinity and extreme insolubility in a wide range of solvents. Royal Society of Chemistry 2019-06-11 /pmc/articles/PMC6713863/ /pubmed/31489159 http://dx.doi.org/10.1039/c9sc02544h Text en This journal is © The Royal Society of Chemistry 2019 https://creativecommons.org/licenses/by-nc/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Brückner, Tobias
Dewhurst, Rian D.
Dellermann, Theresa
Müller, Marcel
Braunschweig, Holger
Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
title Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
title_full Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
title_fullStr Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
title_full_unstemmed Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
title_short Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
title_sort mild synthesis of diboryldiborenes by diboration of b–b triple bonds
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6713863/
https://www.ncbi.nlm.nih.gov/pubmed/31489159
http://dx.doi.org/10.1039/c9sc02544h
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