Cargando…
Bis(catecholato)silanes: assessing, rationalizing and increasing silicon's Lewis superacidity
Although bis(catecholato)silanes have been known for several decades, their substantial Lewis acidity is not yet well described in the literature. Herewith, the synthesis and characterization of multiple substituted bis(catecholato)silanes and their triethylphosphine oxide, fluoride and chloride ion...
Autores principales: | Hartmann, Deborah, Schädler, Marcel, Greb, Lutz |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6713871/ https://www.ncbi.nlm.nih.gov/pubmed/31489160 http://dx.doi.org/10.1039/c9sc02167a |
Ejemplares similares
-
Bis(perfluoropinacolato)silane: A Neutral Silane Lewis Superacid Activates Si−F Bonds
por: Tschernuth, Florian S., et al.
Publicado: (2021) -
Bis(perchlorocatecholato)germane: Hard and Soft Lewis Superacid with Unlimited Water Stability
por: Roth, Daniel, et al.
Publicado: (2020) -
Bis(pertrifluoromethylcatecholato)silane: Extreme Lewis Acidity Broadens the Catalytic Portfolio of Silicon
por: Thorwart, Thaddäus, et al.
Publicado: (2021) -
A free boratriptycene-type Lewis superacid
por: Henkelmann, Marcel, et al.
Publicado: (2021) -
Silicon Tetrakis(trifluoromethanesulfonate): A Simple Neutral Silane Acting as a Soft and Hard Lewis Superacid
por: Hermannsdorfer, André, et al.
Publicado: (2021)