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Bis(catecholato)silanes: assessing, rationalizing and increasing silicon's Lewis superacidity

Although bis(catecholato)silanes have been known for several decades, their substantial Lewis acidity is not yet well described in the literature. Herewith, the synthesis and characterization of multiple substituted bis(catecholato)silanes and their triethylphosphine oxide, fluoride and chloride ion...

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Detalles Bibliográficos
Autores principales: Hartmann, Deborah, Schädler, Marcel, Greb, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6713871/
https://www.ncbi.nlm.nih.gov/pubmed/31489160
http://dx.doi.org/10.1039/c9sc02167a

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