Tuning the Electric Field Response of MOFs by Rotatable Dipolar Linkers

[Image: see text] Recently the possibility of using electric fields as a further stimulus to trigger structural changes in metal–organic frameworks (MOFs) has been investigated. In general, rotatable groups or other types of mechanical motion can be driven by electric fields. In this study we demonstrate how the electric response of MOFs can be tuned by adding rotatable dipolar linkers, generating a material that exhibits paraelectric behavior in two dimensions and dielectric behavior in one dimension. The suitability of four different methods to compute the relative permittivity κ by means of molecular dynamics simulations was validated. The dependency of the permittivity on temperature T and dipole strength μ was determined. It was found that the herein investigated systems exhibit a high degree of tunability and substantially larger dielectric constants as expected for MOFs in general. The temperature dependency of κ obeys the Curie–Weiss law. In addition, the influence of dipolar linkers on the electric field induced breathing behavior was investigated. With increasing dipole moment, lower field strengths are required to trigger the contraction. These investigations set the stage for an application of such systems as dielectric sensors, order–disorder ferroelectrics, or any scenario where movable dipolar fragments respond to external electric fields.