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Localized Electronic Structure of Nitrogenase FeMoco Revealed by Selenium K-Edge High Resolution X-ray Absorption Spectroscopy

[Image: see text] The size and complexity of Mo-dependent nitrogenase, a multicomponent enzyme capable of reducing dinitrogen to ammonia, have made a detailed understanding of the FeMo cofactor (FeMoco) active site electronic structure an ongoing challenge. Selective substitution of sulfur by seleni...

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Detalles Bibliográficos
Autores principales:	Henthorn, Justin T., Arias, Renee J., Koroidov, Sergey, Kroll, Thomas, Sokaras, Dimosthenis, Bergmann, Uwe, Rees, Douglas C., DeBeer, Serena
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2019
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6716209/ https://www.ncbi.nlm.nih.gov/pubmed/31356071 http://dx.doi.org/10.1021/jacs.9b06988

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