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α-Photooxygenation of chiral aldehydes with singlet oxygen

Organocatalytic α-oxygenation of chiral aldehydes with photochemically generated singlet oxygen allows synthesizing chiral 3-substituted 1,2-diols. Stereochemical results indicate that the reaction in the presence of diarylprolinol silyl ethers is highly diastereoselective and that the configuration...

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Detalles Bibliográficos
Autores principales: Walaszek, Dominika J, Jawiczuk, Magdalena, Durka, Jakub, Drapała, Olga, Gryko, Dorota
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6720656/
https://www.ncbi.nlm.nih.gov/pubmed/31501676
http://dx.doi.org/10.3762/bjoc.15.205